925454

AdCyBrettPhos Pd G6 Br

powder

• Synonym(s): Adamantan-1-yl(cyclohexyl)(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphane
• Empirical Formula (Hill Notation): C₄₆H₆₁BrF₃O₂PPd
• Molecular Weight: 920.27
• UNSPSC Code: 41116105
• NACRES: NA.22

Properties

• Product Name: AdCyBrettPhos Pd G6 Br,
• form: powder
• Quality Level: 100
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• SMILES string: Br[Pd](C1=CC=C(C=C1)C(F)(F)F)P(C(C(OC)=CC=C2OC)=C2C(C(C(C)C)=CC(C(C)C)=C3)=C3C(C)C)(C4CCCCC4)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5

Description

Application

AdCyBrettPhos Pd G6 Br is a G₆ Buchwald precatalyst. The G₆ precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

Other Notes

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3