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ALD00352

Sigma-Aldrich

Boc-2-methoxy-L-phenylalanine

97%

Synonym(s):

(S)-2-(tert-butoxycarbonylamino)-3-(2-methoxyphenyl)propanoic acid

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About This Item

Empirical Formula (Hill Notation):
C15H21NO5
CAS Number:
143415-63-8
Molecular Weight:
295.33
MDL number:
MFCD01860640
UNSPSC Code:
12352209
PubChem Substance ID:
329772655
NACRES:
NA.22

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$179.20

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Quality Level

100

assay

97%

form

powder

reaction suitability

reaction type: Boc solid-phase peptide synthesis
reagent type: ligand
reaction type: C-H Activation

mp

157 °C

application(s)

peptide synthesis

storage temp.

2-8°C

SMILES string

OC([C@@H](NC(OC(C)(C)C)=O)CC1=CC=CC=C1OC)=O

InChI

1S/C15H21NO5/c1-15(2,3)21-14(19)16-11(13(17)18)9-10-7-5-6-8-12(10)20-4/h5-8,11H,9H2,1-4H3,(H,16,19)(H,17,18)/t11-/m0/s1

InChI key

QMHKMTAKTUUKEK-NSHDSACASA-N

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This Item
ALD00102ALD00348I8757
Boc-2-methoxy-L-phenylalanine 97%

ALD00352

Boc-2-methoxy-L-phenylalanine

Boc-2-nitro-L-phenylalanine 98% (HPLC)

ALD00102

Boc-2-nitro-L-phenylalanine

Boc-3-[3,4-bis(trifluoromethyl)phenyl]-L-alanine ≥95% (HPLC)

ALD00348

Boc-3-[3,4-bis(trifluoromethyl)phenyl]-L-alanine

4-Iodo-L-phenylalanine

I8757

4-Iodo-L-phenylalanine

form

powder

form

solid

form

powder or solid

form

powder

assay

97%

assay

98% (HPLC)

assay

≥95% (HPLC)

assay

≥98.0% (TLC)

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

−20°C

Quality Level

100

Quality Level

-

Quality Level

100

Quality Level

200

mp

157 °C

mp

-

mp

-

mp

-

reaction suitability

reaction type: Boc solid-phase peptide synthesis

reaction suitability

reaction type: Boc solid-phase peptide synthesis

reaction suitability

reaction type: Boc solid-phase peptide synthesis, reagent type: ligand
reaction type: C-H Activation

reaction suitability

-

Application

Unnatural amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).

Other Notes

Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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