ALD00600

Sigma-Aldrich

Zhu-Yu Auxiliary

98%

Synonym(s):
2,2-Dimethyl aminooxyacetic, 2-(Aminooxy)-2-methylpropanoic acid hydrochloride, 1-Carboxy-1-methylethoxyammonium chloride
Empirical Formula (Hill Notation):
C4H10ClNO3
CAS Number:
Molecular Weight:
155.58
MDL number:

assay

98%

form

powder or crystals

reaction suitability

reagent type: ligand
reaction type: C-H Activation

availability

available only in USA

mp

150-165 °C

Related Categories

Application

The Zhu-Yu Auxiliary was reported by Jin-Quan Yu′s lab to be an effective auxiliary for the Pd(II)-catalyzed ß-C(sp3)-H(hetero)arylation of ketones.

Pictograms

Flame

Signal Word

Danger

Hazard Statements

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Related Content
The Yu program centers around the discovery of catalytic carbon–carbon and carbon–heteroatom bond forming reactions based on C–H activation. Target transformations are selected to enable 1) the use of simple and abundant starting materials such as aliphatic acids, amines and alcohols, and 2) disconnections that drastically shorten the synthesis of a drug molecule or a major class of biologically active compounds.
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