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MilliporeSigma

B33706

Bibenzyl

ReagentPlus®, 99%

Synonym(s):

1,2-Diphenylethane, Dibenzyl

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25 G

$115.00

100 G

$349.35

$115.00


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About This Item

Linear Formula:
C6H5CH2CH2C6H5
CAS Number:
Molecular Weight:
182.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-096-4
Beilstein/REAXYS Number:
508068
MDL number:

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Product Name

Bibenzyl, ReagentPlus®, 99%

InChI key

QWUWMCYKGHVNAV-UHFFFAOYSA-N

InChI

1S/C14H14/c1-3-7-13(8-4-1)11-12-14-9-5-2-6-10-14/h1-10H,11-12H2

SMILES string

C(Cc1ccccc1)c2ccccc2

product line

ReagentPlus®

assay

99%

form

crystals

autoignition temp.

896 °F

bp

284 °C (lit.)

mp

50-53 °C (lit.)

density

1.014 g/mL at 25 °C (lit.)

Quality Level

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1 of 4

This Item
E12508296848343528
assay

99%

assay

99%

assay

99.8%

assay

99%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

50-53 °C (lit.)

mp

−95 °C (lit.)

mp

−95 °C (lit.)

mp

-

form

crystals

form

liquid

form

liquid

form

solid

bp

284 °C (lit.)

bp

136 °C (lit.)

bp

136 °C (lit.)

bp

-

density

1.014 g/mL at 25 °C (lit.)

density

0.867 g/mL at 25 °C (lit.)

density

0.867 g/mL at 25 °C (lit.)

density

-

Application

Bibenzyl is used in the preparation of flame-retardant, high-density rigid polyurethane foams.[1] Additionally, it can also be used to synthesize acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE) inhibitors.[2]

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)


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Flame?retardant and mechanical properties of high?density rigid polyurethane foams filled with decabrominated dipheny ethane and expandable graphite.
Ye L, et al.
Journal of Applied Polymer Science, 111(5), 2372-2380 (2009)
Design, synthesis, and biological evaluation of a new series of biphenyl/bibenzyl derivatives functioning as dual inhibitors of acetylcholinesterase and butyrylcholinesterase.
Wang D M, et al.
Molecules (Basel), 22(1), 172-172 (2017)
Evan G Buchanan et al.
The Journal of chemical physics, 138(6), 064308-064308 (2013-02-22)
The spectroscopy of two flexible hydrocarbons, 1,2-diphenylethane (DPE) and 2,2,2-paracyclophane (TCP) is presented, and a predictive theoretical model for describing the alkyl CH stretch region of these hydrocarbons is developed. Ultraviolet hole-burning spectroscopy identified two isomers of DPE and a
K H Fritzemeier et al.
European journal of biochemistry, 133(3), 545-550 (1983-07-01)
Hydroxy derivatives of 9,10-dihydrophenanthrenes, orchinol and hircinol, were isolated from bulbs of Orchidaceae which had been induced to accumulate phytoalexins. Incorporation of radioactive precursors, L-phenylalanine and various hydroxycinnamic acids, has been investigated by feeding experiments in vivo. m-Coumaric acid and
V P Greer et al.
Journal of enzyme inhibition and medicinal chemistry, 18(5), 431-443 (2003-12-25)
In a search for novel inhibitors of RA-metabolising enzyme inhibitors as potential anti-cancer agents some 1,2-ethandiones, 2-hydroxyethanones and 1-ethylenedioxyethanones based on aryl-substituted 1,2-diphenylethane have been examined. Several of the compounds were weak inhibitors of the non-specific rat liver microsomal P450

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Bonjour, dans le cadre de mes études, je recherche une façon de synthétiser du bibenzyl à partir d'hydrobenzoïne, donc par une réduction. Est-ce comme ça que vous le synthétisez ?

    1 answer
    1. The specific formulation of Bibenzyl is proprietary.

      Helpful?

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