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D62209

trans-1,2-Dichloroethylene

98%

Synonym(s):

trans-1,2-Dichloroethene, trans-Acetylene dichloride

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Size/SKUAvailabilityPrice
5 g

Available to ship TODAYfromMILWAUKEE

$48.00
$36.00
25 g

Available to ship TODAYfromMILWAUKEE

$145.00
100 g

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$174.00

About This Item

Linear Formula:
ClCH=CHCl
CAS Number:
Molecular Weight:
96.94
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-860-2
Beilstein/REAXYS Number:
1420761
MDL number:
Assay:
98%
Form:
liquid

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vapor pressure

5.16 psi ( 20 °C)

Quality Segment

assay

98%

form

liquid

expl. lim.

12.8 %

refractive index

n20/D 1.446 (lit.)

bp

48 °C (lit.)

mp

−50 °C (lit.)

density

1.257 g/mL at 25 °C (lit.)

SMILES string

Cl\C=C\Cl

InChI

1S/C2H2Cl2/c3-1-2-4/h1-2H/b2-1+

InChI key

KFUSEUYYWQURPO-OWOJBTEDSA-N

General description

trans-1,2-Dichloroethylene is an organic solvent used in freon cleaning agents.

Application

trans-1,2-Dichloroethylene can be involved in the synthesis of:
  • (E)-Chloroenynes by reacting with 1-alkyne and piperidine in the presence of PdCl2(PPh3)2 catalyst in ethyl ether as a solvent.
  • (E)-3-trimethylsilyl-1-chloro-1-propene by reacting with trimethylsilylmethylmagnesium chloride (TMSCH2MgCl) in the presence of Co(II) or Co(III) acetylacetonate.
  • trans-1,2-Bis(tri-n-butylstannyl)ethylene which is an important reagent for the synthesis of myriad of natural products.
  • trans-1-Chloroalkenes by reacting with Grignard reagents in the presence of tetrakis(triphenylphosphine)nickel as catalyst.


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This Item
D33209S492148597
assay

98%

assay

96%

assay

98%

assay

-

form

liquid

form

powder

form

-

form

-

refractive index

n20/D 1.446 (lit.)

refractive index

-

refractive index

-

refractive index

n20/D 1.449 (lit.)

mp

−50 °C (lit.)

mp

109-112 °C (lit.)

mp

65-67 °C (lit.)

mp

−80 °C (lit.)

bp

48 °C (lit.)

bp

-

bp

-

bp

60 °C (lit.)

density

1.257 g/mL at 25 °C (lit.)

density

-

density

-

density

1.284 g/mL at 25 °C (lit.)


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

42.8 °F - closed cup

flash_point_c

6.0 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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