D7600
1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose
98%
Synonym(s):
1,2,5,6-diisopropylidene-D-glucose, D-Glucose diacetonide, Diacetone-D-glucose
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$50.28
List Price$54.30Save 7%In StockDetails
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About This Item
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$50.28
List Price$54.30Save 7%In StockDetails
Quality Level
assay
98%
form
powder
optical activity
[α]20/D −18°, c = 1% in H2O
mp
109-113 °C (lit.)
SMILES string
[H][C@@]1(O[C@H]2O[C@@H](O[C@@H]2[C@H]1O)C(Cl)(Cl)Cl)[C@H]3COC(C)(C)O3
InChI
1S/C12H20O6/c1-11(2)14-5-6(16-11)8-7(13)9-10(15-8)18-12(3,4)17-9/h6-10,13H,5H2,1-4H3/t6-,7+,8-,9-,10-/m1/s1
InChI key
KEJGAYKWRDILTF-JDDHQFAOSA-N
1 of 4
This Item | 31460 | 158968 | 310824 |
---|---|---|---|
assay 98% | assay ≥98.0% (TLC) | assay 96% | assay 99% (CP) |
Quality Level 200 | Quality Level 100 | Quality Level 200 | Quality Level 200 |
form powder | form - | form powder or crystals | form powder |
mp 109-113 °C (lit.) | mp 110-111 °C (lit.) | mp 153-156 °C (lit.) | mp 150-152 °C (lit.) |
optical activity [α]20/D −18°, c = 1% in H2O | optical activity [α]20/D −11.5±1°, c = 5% in ethanol | optical activity [α]20/D +52°, c = 10 in H2O | optical activity [α]25/D +52.0°, c = 2 in H2O (trace NH4OH) |
Application
- Biologically active L-acovenose, 6-deoxy-L-idose[1] and, carbanucleoside enantiomers.[2]
- Vinyl ether-based chiral carbohydrate synthon by reacting with acetylene using superbase catalytic systems.[3]
- Fluoro-thiofuranosyl nucleosides of biological importance.[4]
Storage Class
11 - Combustible Solids
wgk_germany
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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