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MilliporeSigma

D87759

7-Diethylamino-4-methylcoumarin

99%

Synonym(s):

Coumarin 1

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5 G

$52.30

100 G

$87.80

500 G

$413.10

$52.30


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About This Item

Empirical Formula (Hill Notation):
C14H17NO2
CAS Number:
Molecular Weight:
231.29
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
202-068-9
MDL number:

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Product Name

7-Diethylamino-4-methylcoumarin, 99%

InChI key

AFYCEAFSNDLKSX-UHFFFAOYSA-N

InChI

1S/C14H17NO2/c1-4-15(5-2)11-6-7-12-10(3)8-14(16)17-13(12)9-11/h6-9H,4-5H2,1-3H3

SMILES string

CCN(CC)c1ccc2C(C)=CC(=O)Oc2c1

assay

99%

form

solid

mp

72-75 °C (lit.)

Quality Level

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1 of 4

This Item
25737063759442631
form

solid

form

solid

form

solid

form

solid

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

assay

99%

assay

99%

assay

≥97.0% (GC)

assay

98%

mp

72-75 °C (lit.)

mp

223-226 °C (lit.)

mp

-

mp

208-210 °C (lit.)

Application

Terbium based metal organic framework may be doped with C1 for potential use in ratiometric temperature sensing.[1] C1 may also be used as a fluorescent photo-initiator that can act as an optical brightener for use in the synthesis of the light emitting diode (LED) based hydrogel.[2]

General description

7-Diethylamino-4-methylcoumarin (C1) is a bichromophoric fluorescent laser dye, which has a laser action at 460 nm.[3][4]

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Vishakha R Shembekar et al.
Biochemistry, 44(19), 7107-7114 (2005-05-11)
We report on a photolabile protecting (caging) group that is new for carboxylic acids. Unlike previously used caging groups for carboxylic acids, it can be photolyzed rapidly and efficiently in the visible wavelength region. The caging group 7-N,N-diethyl aminocoumarin (DECM)
Origin of the dual-band laser emission from 7-diethylamino-4-methylcoumarin (C1) in solution: effect of hydrogen-bonding interaction by hydroxylic molecules
Yip RW and Wen YX
Canadian Journal of Chemistry, 69(9), 1413-1417 (1991)
M A Saleh et al.
Chemosphere, 36(7), 1543-1552 (1998-03-21)
Six different types of fabrics were compared for their ability to protect against human exposure to three different commercial household aerosol insecticides. Fabrics used in this investigation were, 100% cotton, cotton-polyester thermal underwear, cotton-polyester blend (twill), 100% acrylic, 100% wool
Visual scoring system for fluorescent tracer evaluation of dermal exposure to pesticides.
R A Fenske
Bulletin of environmental contamination and toxicology, 41(5), 727-736 (1988-11-01)
Yan Liang et al.
Biomaterials, 100, 76-90 (2016-06-01)
A near infrared (NIR) light responsive chromophore 7-(diethylamino)-4-(hydroxymethyl)-2H-chromen-2-one (DEACM) was synthesized and incorporated to β-cyclodextrins with cRGD functionalized poly(ethylene glycol), the amphiphiles were coordinated with Au nanorods or nanoparticles to load anticancer drug doxorubicin (DOX) for fabricating hybrid nanoparticles. The

Questions

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    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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