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E46607

Ethyl propiolate

99%

Synonym(s):

Ethyl acetylenecarboxylate

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Size/SKUAvailabilityPrice
5 g

Available to ship TODAYfromMILWAUKEE

$62.70
$47.02
25 g

Estimated to ship onSeptember 24, 2026fromMILWAUKEE

$159.00
100 g

Available to ship TODAYfromMILWAUKEE

$393.00
$294.75

About This Item

Linear Formula:
HC≡CCO2C2H5
CAS Number:
Molecular Weight:
98.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-795-8
Beilstein/REAXYS Number:
878250
MDL number:
Assay:
99%
Form:
liquid

$47.02

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Quality Segment

assay

99%

form

liquid

refractive index

n20/D 1.412 (lit.)

bp

120 °C (lit.)

density

0.968 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCOC(=O)C#C

InChI

1S/C5H6O2/c1-3-5(6)7-4-2/h1H,4H2,2H3

InChI key

FMVJYQGSRWVMQV-UHFFFAOYSA-N

Application

Halogenated derivatives were used as substrates for direct, asymmetric alkynylation of cyclic β-ketoesters using chiral phase-transfer catalysts.[1] Also employed in a one-pot , four-component synthesis of benzene-1,2,3,5-tetracarboxylates promoted by Ph3P.

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This Item
171859112305419885
assay

99%

assay

99%

assay

99%

assay

98%

density

0.968 g/mL at 25 °C (lit.)

density

0.945 g/mL at 25 °C (lit.)

density

0.888 g/mL at 25 °C (lit.)

density

0.919 g/mL at 25 °C (lit.)

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

refractive index

n20/D 1.412 (lit.)

refractive index

n20/D 1.408 (lit.)

refractive index

n20/D 1.384 (lit.)

refractive index

n20/D 1.418 (lit.)

bp

120 °C (lit.)

bp

103-105 °C (lit.)

bp

99 °C (lit.)

bp

52-53 °C/27 mmHg (lit.)

form

liquid

form

liquid

form

liquid

form

liquid


pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

77.0 °F - closed cup

flash_point_c

25 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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