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MilliporeSigma

M72609

N-Methylpiperidine

99%

Synonym(s):

1-Methylpiperidine

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$41.70

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$158.00

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About This Item

Empirical Formula (Hill Notation):
C6H13N
CAS Number:
626-67-5
Molecular Weight:
99.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24897150
EC Number:
210-959-9
Beilstein/REAXYS Number:
1073
MDL number:
MFCD00006491
Assay:
99%

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Product Name

N-Methylpiperidine, 99%

InChI key

PAMIQIKDUOTOBW-UHFFFAOYSA-N

InChI

1S/C6H13N/c1-7-5-3-2-4-6-7/h2-6H2,1H3

SMILES string

CN1CCCCC1

assay

99%

refractive index

n20/D 1.4378 (lit.)

bp

106-107 °C (lit.)

density

0.816 g/mL at 25 °C (lit.)

Quality Level

200

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This Item
D46904239356D98807
N-Methylpiperidine 99%

Sigma-Aldrich

M72609

N-Methylpiperidine

N,N-Dibutylformamide 99%

Sigma-Aldrich

D46904

N,N-Dibutylformamide

N,N-Dimethylethylamine 99%

Sigma-Aldrich

239356

N,N-Dimethylethylamine

N,N-Diethylnicotinamide 99%

Sigma-Aldrich

D98807

N,N-Diethylnicotinamide

assay

99%

assay

99%

assay

99%

assay

99%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

refractive index

n20/D 1.4378 (lit.)

refractive index

n20/D 1.44 (lit.)

refractive index

n20/D 1.372 (lit.)

refractive index

n20/D 1.524 (lit.)

bp

106-107 °C (lit.)

bp

120 °C/15 mmHg (lit.)

bp

36-38 °C (lit.)

bp

296-300 °C (lit.)

density

0.816 g/mL at 25 °C (lit.)

density

0.864 g/mL at 25 °C (lit.)

density

0.675 g/mL at 25 °C (lit.)

density

1.06 g/mL at 25 °C (lit.)

Application

Reactant for:
  • sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines
  • One-pot synthesis of Z-cinnamic acids

Reactant for synthesis of:
  • Unsymmetrical ureas
  • Antibacterial imidazolium, pyrrolidinium, and piperidinium salts
  • C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling
  • Multi-targeted inhibitors of insulin-like growth factor-1 receptor and members of ErbB-family receptor kinases

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

37.4 °F - closed cup

flash_point_c

3 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB1572
STBL3379
STBL4355
STBK7924
STBK9940

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Oscar B Torres et al.
Analytical and bioanalytical chemistry, 410(16), 3885-3903 (2018-04-21)
We describe for the first time a method that utilizes microscale thermophoresis (MST) technology to determine polyclonal antibody affinities to small molecules. Using a novel type of heterologous MST, we have accurately measured a solution-based binding affinity of serum antibodies
Xuenan Li et al.
Journal of food science, 85(9), 2754-2761 (2020-08-15)
N,N-dimethylpiperidinium (mepiquat) is a new process-induced compound formed from natural constituents during the cooking process. Mepiquat was first found in coffee and cereal products, but its formation mechanism in coffee is still unclear. In the current study, Arabica and Robusta
Nithyanandhan Jayaraj et al.
Langmuir : the ACS journal of surfaces and colloids, 25(24), 13820-13832 (2010-06-22)
Supramolecular complexation behavior of cucurbiturils with paramagnetic nitroxide spin probes was examined by (1)H NMR, X-ray diffraction studies of crystals, computation, and EPR. Both cucurbit[7]uril (CB7) and cucurbit[8]uril (CB8) form a 1:1 complex with 4-(N,N,N-trimethylammonium)-2,2,6,6-tetramethylpiperidinyl-N-oxy bromide (CAT1). The structure of
A Kolocouris et al.
The Journal of organic chemistry, 66(15), 4989-4997 (2001-07-21)
When a 1-adamantyl or a 2-adamantyl substituent is introduced at the 2-position in N-methylpiperidine, four different chair conformations are possible. Experimental observation using dynamic NMR spectroscopy and molecular mechanics calculations agree that the chair conformation with an equatorial adamantyl group
[The mechanism of reverse inhibition of cholinesterases by thionphosphonates].
N N Kovalev et al.
Izvestiia Akademii nauk SSSR. Seriia biologicheskaia, (6)(6), 926-929 (1988-11-01)
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