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T7394
N,N,N′,N′-Tetramethyl-p-phenylenediamine
99%, powder
Synonym(s):
TMPD, TMPDA, TMPPD, Wurster’s reagent
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5 G
$123.00
25 G
$313.00
About This Item
Linear Formula:
C6H4[N(CH3)2]2
CAS Number:
Molecular Weight:
164.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-831-6
Beilstein/REAXYS Number:
1564025
MDL number:
Assay:
99%
Form:
flakes, powder
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InChI key
CJAOGUFAAWZWNI-UHFFFAOYSA-N
InChI
1S/C10H16N2/c1-11(2)9-5-7-10(8-6-9)12(3)4/h5-8H,1-4H3
SMILES string
CN(C)c1ccc(cc1)N(C)C
assay
99%
form
flakes, powder
color
off-white to brown
bp
260 °C (lit.)
mp
49-51 °C (lit.)
Quality Level
Related Categories
1 of 4
This Item | |||
|---|---|---|---|
| assay 99% | assay ≥95% | assay ≥97.0% (AT) | assay ≥99% |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| mp 49-51 °C (lit.) | mp 222-224 °C (lit.) | mp 222-224 °C (lit.) | mp - |
| form flakes, powder | form powder | form powder | form - |
| bp 260 °C (lit.) | bp - | bp - | bp 145-146 °C (lit.) |
| color off-white to brown | color off-white to gray-brown | color - | color - |
General description
N,N,N′,N′-Tetramethyl-p-phenylenediamine (TMPDA) is a redox reagent with low ionization potential widely used as an electron donor for photosystem I. It also acts as an electron acceptor in photosystem II.
Application
N,N,N′,N′-Tetramethyl-p-phenylenediamine (TMPDA) can be used:
- In the flow injection analysis of benzoyl peroxide.
- To study photoinduced electron transfer to halogenated solvents.
Disclaimer
May darken in storage.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
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Flow injection analysis of benzoyl peroxide using N, N, N, N-tetramethyl-p-phenylenediamine (TMPDA) and surfactants
Pharr DY & Tomsyck JA
Analytical Letters, 42(5), 821-832 (2009)
Ultrafast photoinduced electron transfer from N, N, N′ , N′ -tetramethyl-p-phenylenediamine and N, N, N′ , N′ -tetramethylbenzidine to dichloromethane
Boilet L, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 163(3), 529-536 (2004)
Interaction of N, N, N′ ,N′ -tetramethyl-p-phenylenediamine with photosystem II as revealed by thermoluminescence: reduction of the higher oxidation states of the Mn cluster and displacement of plastoquinone from the QB niche
Gauthier A, et al.
Biochimica et Biophysica Acta, 1757(11), 1547-1556 (2006)
P P Bawol et al.
Physical chemistry chemical physics : PCCP, 20(33), 21447-21456 (2018-08-09)
The reversibility of current Li-O2 batteries suffers from high charging overpotentials. To address this problem, the use of redox mediators has been proposed, which are supposed to improve the sluggish reaction kinetics of the oxygen evolution reaction via a solution
Toshiaki Miura
Chemico-biological interactions, 236, 67-73 (2015-04-30)
To investigate the mechanisms of cardiotoxicity induced by adriamycin (ADM), the enzymatic activities of ADM-Fe(3+), including the peroxidase and lipoxygenase (LOX) activity, and participation of active oxygen species in the damage to biological components were examined. ADM-Fe(3+), but not ADM
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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