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T81906

Sigma-Aldrich

Triphenylarsine

97%

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Synonym(s):
Arsinetriphenyl
Linear Formula:
(C6H5)3As
CAS Number:
Molecular Weight:
306.23
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

97%

form

solid

reaction suitability

reagent type: catalyst

mp

58-61 °C (lit.)

SMILES string

c1ccc(cc1)[As](c2ccccc2)c3ccccc3

InChI

1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

BPLUKJNHPBNVQL-UHFFFAOYSA-N

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1 of 4

This Item
489662615951292125
vibrant-m

T81906

Triphenylarsine

vibrant-m

489662

Palmitic acid-2,2-d2

vibrant-m

615951

Palmitic acid-16,16,16-d3

vibrant-m

292125

Palmitic acid-1-13C

assay

97%

assay

99% (CP)

assay

≥99% (CP)

assay

99% (CP)

mp

58-61 °C (lit.)

mp

61-64 °C

mp

61-64 °C

mp

61-64 °C

reaction suitability

reagent type: catalyst

reaction suitability

-

reaction suitability

-

reaction suitability

-

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

General description

Triphenylarsine is an organoarsenic compound mainly used as a ligand and reagent in organic synthesis. It can also be used as a vapor deposition precursor to prepare nanomaterials.

Application

Triphenylarsine can be used:
  • As a CVD precursor to prepare As-doped carbon nanotubes with enhanced activity and long-term durability for the oxygen reduction reaction.
  • As an arsenic source to synthesize InAs nanocrystals.
  • As a ligand to accelerate the reaction rate of the Stille coupling reaction.
  • To prepare trichromophoric sensitizer for dye-sensitized solar cells.

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3


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Novel As-doped, As and N-codoped carbon nanotubes as highly active and durable electrocatalysts for O2 reduction in alkaline medium
Ziwu Liu, et al.
Journal of Power Sources, 306, 535-540 (2016)
Panchromatic Trichromophoric Sensitizer for Dye-Sensitized Solar Cells Using Antenna Effect
Julien Warnan, et al
Organic Letters, 13, 3944-3947 (2011)
Tertiary arsine ligands for the Stille coupling reaction
Akane Chishiro, et al.
Dalton Transactions, 51, 95-103 (2022)
Benzene-thermal route to InP and InAs nanocrystals using triphenylphosphine and triphenylarsine as pnicogen sources
Junli Wang and Qing Yang
Chemistry Letters (Jpn), 37, 306-307 (2008)
Ryoto Inaba et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(59), 13400-13407 (2020-07-15)
Efficient catalytic arsa-Wittig reactions have been developed by using 1-phenylarsolane as a catalyst. A wide array of aldehydes was converted to the corresponding olefins in high yields with moderate to excellent E stereoselectivity in the presence of a catalytic amount

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