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MilliporeSigma

T89605

Tropinone

99%

Synonym(s):

8-Methyl-8-azabicyclo[3.2.1]octan-3-one

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About This Item

Empirical Formula (Hill Notation):
C8H13NO
CAS Number:
532-24-1
Molecular Weight:
139.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24900577
EC Number:
208-530-6
Beilstein/REAXYS Number:
2329
MDL number:
MFCD00005549
Assay:
99%

Key Documents

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Product Name

Tropinone, 99%

InChI

1S/C8H13NO/c1-9-6-2-3-7(9)5-8(10)4-6/h6-7H,2-5H2,1H3/t6-,7+

InChI key

QQXLDOJGLXJCSE-KNVOCYPGSA-N

SMILES string

CN1[C@@H]2CC[C@H]1CC(=O)C2

assay

99%

bp

113 °C/25 mmHg (lit.)

mp

40-44 °C (lit.)

storage temp.

2-8°C

Quality Level

100

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1 of 4

This Item
A0257PHL84099PHL84089
Tropinone 99%

Sigma-Aldrich

T89605

Tropinone

Atropine sulfate salt monohydrate ≥97% (TLC), crystalline

Sigma-Aldrich

A0257

Atropine sulfate salt monohydrate

Pseudotropine phyproof® Reference Substance

PHL84099

Pseudotropine

Nortropinone hydrochloride phyproof® Reference Substance

PHL84089

Nortropinone hydrochloride

assay

99%

assay

≥97% (TLC)

assay

≥95.0% (GC)

assay

≥95.0% (GC)

Quality Level

100

Quality Level

200

Quality Level

-

Quality Level

-

mp

40-44 °C (lit.)

mp

189-192 °C (A) (lit.)

mp

-

mp

-

bp

113 °C/25 mmHg (lit.)

bp

-

bp

-

bp

-

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

2-8°C

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

194.0 °F - closed cup

flash_point_c

90 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
WXBD9113V
MKCM7258
MKCL3941
MKCK8483
MKCH6139

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A Portsteffen et al.
Phytochemistry, 37(2), 391-400 (1994-09-01)
In tropane-alkaloid producing plants and root cultures, the reduction of tropinone is a branch-point in secondary metabolism. Two different reductases stereospecifically form the isomeric alcohols tropine (tropan-3 alpha-ol) and pseudotropine (tropan-3 beta-ol). We describe here the purification and characterization of
Andrea Brock et al.
The Plant journal : for cell and molecular biology, 54(3), 388-401 (2008-01-29)
Tropane alkaloids typically occur in the Solanaceae and are also found in Cochlearia officinalis, a member of the Brassicaceae. Tropinone reductases are key enzymes of tropane alkaloid metabolism. Two different tropinone reductases form one stereoisomeric product each, either tropine for
Solid-phase synthesis of tertiary N-methyl amines including tropanes.
Michal Sienkiewicz et al.
Journal of combinatorial chemistry, 12(1), 5-8 (2009-11-03)
Jesús Marín-Sáez et al.
Journal of chromatography. A, 1518, 46-58 (2017-09-06)
Tropane alkaloids are a wide group of substances that comprises more than 200 compounds occurring especially in the Solanaceae family. The main aim of this study is the development of a method for the analysis of the principal tropane alkaloids
Some features of modern pharmacology.
V V Zakusov
Pharmacological research communications, 12(3), 233-238 (1980-03-01)
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