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Organic Syntheses via Boranes: Volume 3 Suzuki Coupling

A. Suzuki and H. C. Brown, Aldrich Chemical Co., 2003, 314 pp., hard cover

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publication info

A. Suzuki and H. C. Brown, Aldrich Chemical Co., 2003, 314 pp., hard cover

General description

In this volume various aspects of the Suzuki coupling reaction are discussed such as preparation of organoboranes for Suzuki coupling and coupling with Alkyl-, Alkenyl-, Alkynyl- and Arylboranes.

Table of Contents

1 Introduction:
2 Preparation of Organoboranes Desirable for Suzuki Coupling
2.1 Hydroboration of Alkenes and Alkynes
2.2 Addition of Heteroatom-Boron Bonds to Alkynes
2.3 Diboration of Alkynes
2.4 Preparation from Organolithium and Grignard Reagents
2.5 Preparation of Arylboronic Esters by the Reaction of Aryl Halides with (Alkoxy)diboranes
2.6 Miscellaneous Reactions
2.7 Procedures
3 Suzuki Coupling with 1-Alkenylboranes
3.1 With 1-Alkenyl Halides
3.2 With Aryl Halides
3.3 Miscellaneous
3.4 Procedures
4 Suzuki Coupling with Arylboranes, Part 1
4.1 With Aryl Halides: Synthesis of Biaryls Suzuki Coupling with Arylboranes, Part 2
Suzuki Coupling with Arylboranes, Part 3
4.2 With 1-Alkenyl Halides
4.3 With Other Organic Halides Including Aryl Chlorides and Electrophiles
4.4 Miscellaneous
4.5 Applications in Polymer Chemistry Suzuki Coupling with Arylboranes, Part 4
4.6 Procedures
5 Suzuki Coupling with 1-Alkynylboranes
5.1 Reaction with Aryl and 10Alkenyl Halides
5.2 Procedures
6 Suzuki Coupling with Alkylboranes
6.1 With Alkenyl Halides
6.2 With Aryl Halides
6.3 Mechanism of the Alkylborane Reaction
6.4 Miscellaneous
6.5 Procedures
7 Miscellaneous Suzuki Coupling
7.1 With Other Organic Halides and Boranes
7.2 Head-to-Tail Coupling
7.3 Carbonylative Coupling
7.4 Alkoxycarbonylation and Dimerization
7.5 Procedures
8 The Mechanism of Palladium-Catalyzed Coupling of Organic Boranes
8.1 Cross-Coupling Reactions
8.2 Other Catalytic Processes by Transition-Metal Complexes and Organoboranes

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