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1.00495

Oxalic acid dihydrate

for analysis EMSURE® ACS,ISO,Reag. Ph Eur

Synonym(s):

Oxalic acid dihydrate, Ethanedioic acid

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Pack SizeSKUAvailabilityPrice
100 g
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$152.00
500 g
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$257.00
1 kg
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$436.00
25 kg
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$7,420.00

About This Item

Linear Formula:
(COOH)2 · 2 H2O
CAS Number:
Molecular Weight:
126.07
UNSPSC Code:
12352106
EC Index Number:
205-634-3
NACRES:
NA.21
MDL number:
Assay:
99.5-102.0% (manganometric)
Form:
solid
Grade:
ACS reagent

$152.00


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grade

ACS reagent

Quality Level

agency

reag. ISO, reag. Ph. Eur.

vapor pressure

0.000312 hPa ( 25 °C)

product line

EMSURE®

assay

99.5-102.0% (manganometric)

form

solid

potency

375 mg/kg LD50, oral (Rat)

impurities

≤50 ppm Insoluble matter

ign. residue

≤100 ppm (as sulfate)

pH

1.5 (10 g/L in H2O)

bp

149-160 °C/1013 hPa (decomposition)

mp

98-100 °C

transition temp

flash point 157 °C (decomposition)

solubility

>100 g/L

density

1.65 g/cm3 at 20 °C

bulk density

813 kg/m3

anion traces

chloride (Cl-): ≤5 ppm, sulfate (SO42-): ≤50 ppm

cation traces

Ca: ≤10 ppm, Fe: ≤2 ppm, N: ≤10 ppm, heavy metals: ≤5 ppm, heavy metals (as Pb): ≤5 ppm

storage temp.

2-30°C

SMILES string

[O+H3].[O+H3].[O-]C(=O)C(=O)[O-]

InChI

1S/C2H2O4.2H2O/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H2

InChI key

GEVPUGOOGXGPIO-UHFFFAOYSA-N

Application


  • In Situ Investigation of a Self-Accelerated Cocrystal Formation by Grinding Pyrazinamide with Oxalic Acid.: This study investigates the in situ cocrystal formation of pyrazinamide and oxalic acid dihydrate, emphasizing the self-accelerating nature of the process and its implications for pharmaceutical development (Kulla et al., 2016).

  • Deuterium MAS NMR studies of dynamics on multiple timescales: histidine and oxalic acid.: This article examines the dynamics of oxalic acid dihydrate and histidine using deuterium magnetic angle spinning nuclear magnetic resonance, providing insights into molecular motions on various timescales (Chan-Huot et al., 2015).

Analysis Note

Assay (manganometric): 99.5 - 102.0 %
Insoluble matter: ≤ 50 ppm
Chloride (Cl): ≤ 5 ppm
Sulfate (SO₄): ≤ 50 ppm
Total nitrogen (N): ≤ 10 ppm
Heavy metals (as Pb): ≤ 5 ppm
Heavy metals (ACS): ≤ 5 ppm
Ca (Calcium): ≤ 10 ppm
Fe (Iron): ≤ 2 ppm
Readily carbonisable substance: passes test
Residue on ignition (as sulfate): ≤ 100 ppm
Corresponds to ACS,ISO,Reag. Ph Eur

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

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This Item
1.9301833506O0376
grade

ACS reagent

grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

-

assay

99.5-102.0% (manganometric)

assay

-

assay

≥99.5% (manganometric)

assay

≥99.0% (GC)

agency

reag. ISO, reag. Ph. Eur.

agency

-

agency

USP/NF, reag. ISO, reag. Ph. Eur.

agency

-

Quality Level

300

Quality Level

200

Quality Level

200

Quality Level

200

form

solid

form

-

form

crystals

form

-

pH

1.5 (10 g/L in H2O)

pH

-

pH

-

pH

-


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 1



Certificates of Analysis (COA)

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Global Trade Item Number

SKUGTIN
100495100004022536006925
100495010004022536006895
100495050004022536006901
100495902504022536006956

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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