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MilliporeSigma

1.03965

Iron(II) sulfate heptahydrate

greener alternative

for analysis EMSURE® ACS,ISO,Reag. Ph Eur

Synonym(s):

Iron(II) sulfate heptahydrate, Iron

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100 G

$77.70

500 G

$168.00

1 KG

$259.00

5 KG

$906.00

25 KG

$6,220.00

$77.70


Estimated to ship onJune 04, 2026Details

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About This Item

Empirical Formula (Hill Notation):
FeO4S · 7H2O
CAS Number:
Molecular Weight:
278.01
UNSPSC Code:
12352302
EC Index Number:
231-753-5
NACRES:
NA.21
MDL number:
Assay:
99.5-102.0% (manganometric)
Grade:
ACS reagent
Form:
solid

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SMILES string

[Fe+2].[S](=O)(=O)([O-])[O-].O.O.O.O.O.O.O

InChI

1S/Fe.H2O4S.7H2O/c;1-5(2,3)4;;;;;;;/h;(H2,1,2,3,4);7*1H2/q+2;;;;;;;;/p-2

InChI key

SURQXAFEQWPFPV-UHFFFAOYSA-L

grade

ACS reagent

agency

reag. ISO, reag. Ph. Eur.

product line

EMSURE®

assay

99.5-102.0% (manganometric)

form

solid

potency

319 mg/kg LD50, oral (Rat)

greener alternative product characteristics

Design for Energy Efficiency
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impurities

≤0.01% Insoluble matter

pH

3-4 (20 °C, 50 g/L in H2O)

mp

>60 °C (Elimination of water of crystallisation)

density

1.89 g/cm3 at 20 °C

bulk density

600 kg/m3

anion traces

chloride (Cl-): ≤0.0005%, phosphate (PO43-): ≤0.001%

cation traces

As: ≤0.0002%, Ca: ≤0.005%, Co: ≤0.0025%, Cr: ≤0.0050%, Cu: ≤0.001%, Fe3+: ≤0.02%, K: ≤0.002%, Mg: ≤0.002%, Mn: ≤0.05%, N: ≤0.001%, Na: ≤0.02%, Ni: ≤0.0050%, Pb: ≤0.0005%, Zn: ≤0.0050%, heavy metals (as Pb): ≤0.005%

greener alternative category

storage temp.

15-25°C

Quality Level

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Show Differences

1 of 4

This Item
123541.03963215422
form

solid

form

crystals

form

crystalline, solid

form

powder or crystals

assay

99.5-102.0% (manganometric)

assay

99.5-104.5% (manganometric)

assay

-

assay

≥99.0%

Quality Level

300

Quality Level

200

Quality Level

500

Quality Level

200

grade

ACS reagent

grade

-

grade

-

grade

ACS reagent

anion traces

chloride (Cl-): ≤0.0005%, phosphate (PO43-): ≤0.001%

anion traces

chloride (Cl-): ≤100 mg/kg

anion traces

-

anion traces

chloride (Cl-): ≤0.001%, phosphate (PO43-): ≤0.001%

impurities

≤0.01% Insoluble matter

impurities

organic volatile impurities, complies (GC), residual solvents, complies, ≤0.005% heavy metals (as Pb)

impurities

-

impurities

≤0.01% insolubles, ≤0.05% Substances not pptd by NH4OH

Analysis Note

Assay (manganometric): 99.5 - 102.0 %
Identity: passes test
Appearance of solution: passes test
Insoluble matter: ≤ 0.01 %
pH-value (5 %; water): 3.0 - 4.0
Chloride (Cl): ≤ 0.0005 %
Phosphate (PO₄): ≤ 0.001 %
Total nitrogen (N): ≤ 0.001 %
Heavy metals as Pb: ≤ 0.005 %
As (Arsenic): ≤ 0.0002 %
Ca (Calcium): ≤ 0.005 %
Cr (Chromium): ≤ 0.0050 %
Cu (Copper): ≤ 0.001 %
Fe III (Iron III): ≤ 0.02 %
K (Potassium): ≤ 0.002 %
Mg (Magnesium): ≤ 0.002 %
Mn (Manganese): ≤ 0.05 %
Na (Sodium): ≤ 0.02 %
Ni (Nickel): ≤ 0.0050 %
Pb (Lead): ≤ 0.0005 %
Zn (Zinc): ≤ 0.0050 %
Co (Cobalt): ≤ 0.0025 %
Substance not precipitated by ammonium hydroxide: ≤ 0.1 %
Corresponds to ACS,ISO,Reag. Ph Eur

General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. IRON(II) SULFATE HEPTAHYDRATE is essential for developing greener energy solutions, particularly in iron-based lithium-ion batteries. Its eco-friendly properties enhance energy storage efficiency, reduce reliance on harmful materials, and support the advancement of sustainable technologies. Click here for more information.

Other Notes

Replaces: FX0260-1

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Questions

1–4 of 4 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. Can this be used for mammalian cell culture supplementation?

    1 answer
    1. The product has undergone no testing to determine its suitability for cell culture applications. A product that has been tested for cell culture use is F8633.

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  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. To whom it may concern, We keep Iron(II) sulfate heptahydrate at room temperature over the years. I am wondering if there is a chance it can get oxidized?

    1 answer
    1. Iron(II) sulfate heptahydrate can oxidize over time, particularly when exposed to air. The recommended storage temperature is 15-25°C. The lot-specific shelf life is available on the Certificate of Analysis.

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