8.18212

1,3-Dimethyl-2-imidazolidinone

for synthesis

• Synonym(s): 1,3-Dimethyl-2-imidazolidinone, Dimethylethylene urea, DMI, DMEU
• Empirical Formula (Hill Notation): C₅H₁₀N₂O
• CAS Number: 80-73-9
• Molecular Weight: 114.15
• MDL number: MFCD00003188
• UNSPSC Code: 12352115
• EC Index Number: 201-304-8
• NACRES: NA.22

Properties

• vapor pressure: <1 hPa ( 20 °C)
• Quality Level: 200
• assay: ≥99.0% (GC)
• form: liquid
• autoignition temp.: 305 °C
• potency: 1261 mg/kg LD₅₀, oral (Rat); 986 mg/kg LD₅₀, skin (Rabbit)
• expl. lim.: 1.3-8.4 % (v/v)
• kinematic viscosity: 1.43 cSt(40 °C)
• mp: 8 °C
• transition temp: flash point 114 °C
• density: 1.056 g/cm³ at 20 °C
• storage temp.: 2-30°C
• SMILES string: N1(CCN(C1=O)C)C
• InChI: 1S/C5H10N2O/c1-6-3-4-7(2)5(6)8/h3-4H2,1-2H3
• InChI key: CYSGHNMQYZDMIA-UHFFFAOYSA-N

Description

Application

• Concentration of 1, 3-dimethyl-2-imidazolidinone in aqueous solutions by sweeping gas membrane distillation: from bench to industrial scale. This study explores the characteristics and applications of 1,3-dimethyl-2-imidazolidinone (DMI) as a dipolar aprotic solvent, between tetrahydrofuran (THF) and hexamethylphosphoramide (HMPA) (R Abejón, et al., 2019).


• Photocatalyzed iron-based ATRP of methyl methacrylate using 1, 3-dimethyl-2-imidazolidinone as both solvent and ligand. This paper discusses the use of DMI in green solvent applications, highlighting its dual role as a solvent and ligand in polymerization processes (J Wu, et al., 2017).


• Perovskite solar cells fabricated by using an environmental friendly aprotic polar additive of 1, 3-dimethyl-2-imidazolidinone. The study showcases the application of DMI in improving the quality of perovskite films for solar cells (L Zhi, et al., 2017).

Analysis Note

Assay (GC, area%): ≥ 99.0 % (a/a)
Identity (IR): passes test
Density (d 20 °C/ 4 °C): 1.055 - 1.057
Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

Safety Information

• pictograms: GHS05,GHS07,GHS08
• signalword: Danger
• hcodes: H302 - H318 - H361fd
• pcodes: P201 - P202 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 2
• flash_point_f: 219.2 °F - closed cup
• flash_point_c: 104 °C - closed cup