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MilliporeSigma

LX0350

Lithium Hydroxide, Monohydrate

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Meets ACS Specifications GR ACS

Synonym(s):

Lithium Hydroxide, Monohydrate, Lithium Hydroxide

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About This Item

Empirical Formula (Hill Notation):
HLiO · xH2O
CAS Number:
Molecular Weight:
23.95 (anhydrous basis)
UNSPSC Code:
12352302
EC Index Number:
215-183-4
MDL number:
Assay:
≥98.0%
Grade:
ACS reagent
Form:
crystals
Solubility:
124 g/L

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SMILES string

[Li+].[O-H].O

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

grade

ACS reagent

assay

≥98.0%

form

crystals

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impurities

≤0.01% Insoluble matter

color

white

pH

12 (50 °C, 50 g/L in H2O)

bp

924 °C/1013 hPa (decomposition)

mp

424 °C

solubility

124 g/L

anion traces

chloride (Cl-): ≤0.01%, lithium carbonate (Li2CO3): ≤2%, sulfate (SO42-): ≤0.05%

cation traces

Fe: ≤0.002%, heavy metals: ≤0.002%

greener alternative category

shipped in

ambient

storage temp.

room temp

Quality Level

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This Item
402974254274450197
form

crystals

form

powder, crystals or granules

form

crystalline

form

solid

assay

≥98.0%

assay

≥98.0%

assay

99.95% trace metals basis

assay

99.995% trace metals basis

solubility

124 g/L

solubility

water: soluble 216 g/L at 20 °C

solubility

-

solubility

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

impurities

≤0.01% Insoluble matter

impurities

≤0.01% insolubles, ≤2.0% Li2CO3

impurities

≤550.0 ppm Trace Metal Analysis

impurities

≤55.0 ppm Trace Metal Analysis

mp

424 °C

mp

-

mp

-

mp

-

Analysis Note

Assay: 98.0% min
Chloride (Cl): 0.01% max
Color: White
Form: Crystals
Heavy Metals (by ICP-OES): 0.002% max
Insoluble matter: 0.01% max
Iron (Fe): 0.002% max
Lithium carbonate (Li2CO3): 2.0% max
Sulfate (SO4): 0.05% max

Application

Lithium Hydroxide, Monohydrate can be used as:
  • A catalyst to synthesize 3,4-disubstituted pyrrole derivatives by reacting with aromatic aldehydes and enolisable ketones via in situ formation of chalcones.[1]
  • A precursor for the fabrication of lithium-ion battery cathode material.[2]
  • A starting material to synthesize lithium cobalt oxide (LiCoO2, a positive electrode material) by hydrothermal reaction with cobalt (II) nitrate and hydrogen peroxide.[3]

General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Lithium hydroxide monohydrate supports cleaner technologies as a key precursor for high-performance lithium-ion batteries. Click here for more information.

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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Lithium hydroxide mediated synthesis of 3, 4-disubstituted pyrroles
Sharma R, et al.
Royal Society of Chemistry Advances, 3(34) (2013)
Hydrothermal synthesis of LiCoO2 for lithium rechargeable batteries
Burukhin A, et al.
Solid State Ionics, 151(1-4) (2002)
Production of Battery Grade Lithium Hydroxide Monohydrate Using Barium Hydroxide Causticizing Agent
Liu H and Azimi G
Resources, Conservation and Recycling, 179 (2022)

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