All Photos(1)

30-2480

Sigma-Aldrich

Tin(II) chloride dihydrate

JIS special grade, ≥97.0%

Synonym(s):
Stannous chloride dihydrate
Linear Formula:
SnCl2 · 2H2O
CAS Number:
Molecular Weight:
225.65
MDL number:
PubChem Substance ID:

grade

JIS special grade

assay

≥97.0%

form

solid

reaction suitability

reagent type: catalyst
core: tin

availability

available only in Japan

bp

652 °C (lit.)

mp

37-38 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

O.O.Cl[SnH2]Cl

InChI

1S/2ClH.2H2O.Sn/h2*1H;2*1H2;/q;;;;+2/p-2

InChI key

FWPIDFUJEMBDLS-UHFFFAOYSA-L

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

Target Organs

Cardio-vascular system, Respiratory system

Storage Class Code

8B - Non-combustible, corrosive hazardous materials

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Sher Bahadar Khan
Carbohydrate polymers, 242, 116286-116286 (2020-06-23)
Efficient nano-catalysts based-on metal nanoparticles (copper, silver and iron) supported on carbohydrate polymer (cotton cellulose) nanocomposite with long-term stability and efficient hydrogen production and removal of organic pollutants has been developed. The catalytic efficiency of the developed materials was evaluated...
David J Hallett et al.
Organic & biomolecular chemistry, 10(30), 6130-6158 (2012-04-20)
Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoates 49. This stereoselectivity, controlled by the chirality of the stannane, dominates over any intrinsic stereochemical...
Grégory Dupeyre et al.
Organic & biomolecular chemistry, 9(22), 7780-7790 (2011-10-07)
A six-step one-pot reaction was designed for synthesizing homodimeric 7-phenylindolo[3,2-a]carbazoles from 1H-indoles and β-nitrostyrenes, in the presence of SnCl(2)·2H(2)O. The reactions proceeded under very mild conditions and the desired heterocycles were obtained in moderate to good yields. An unprecedented mechanism...
Amit Pratap Singh et al.
Journal of the American Chemical Society, 134(10), 4998-5003 (2012-02-15)
Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl(+)) and anionic (MCl(3)(-)) species...
Olivier Germay et al.
Organic & biomolecular chemistry, 10(48), 9709-9733 (2012-11-17)
The tin(IV) chloride mediated cyclisation of (Z)-homoallylic alcohols using phenylselenenyl chloride or phthalimide in the presence of a Lewis acid followed by reductive removal of the phenylselenenyl group was found to give 2,5-cis-disubstituted tetrahydrofurans with excellent stereocontrol. Using this procedure...

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