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Trioctylphosphine oxide

greener alternative

≥98.5% (GC), for extraction analysis

Synonym(s):

(Oct)3PO, TOPO®

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Size/SKUAvailabilityPrice
10 g
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$111.00

About This Item

Linear Formula:
[CH3(CH2)7]3PO
CAS Number:
Molecular Weight:
386.63
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
EC Number:
201-121-3
MDL number:
Beilstein/REAXYS Number:
1796648

$111.00


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Product Name

Trioctylphosphine oxide, for extraction analysis, ≥98.5%

Quality Segment

assay

≥98.5% (GC), ≥98.5%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

greener alternative product characteristics

Catalysis
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sustainability

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impurities

≤0.2% free acid (as H3PO4), ≤0.5% water

bp

201-202 °C/2 mmHg (lit.)

mp

50-52 °C (lit.), 52-55 °C

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤10 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤10 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

functional group

phosphine oxide

greener alternative category

SMILES string

CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51OP/c1-4-7-10-13-16-19-22-26(25,23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

ZMBHCYHQLYEYDV-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Catalyst in:
  • Preparation of tetradentate planar-chiral hydroxy-substituted ferrocenecarboxaldimine Schiff base ligands
  • Reactions of allyl esters with hydrosilanes
  • Asymmetric cyanosilylation of aldehydes
  • Preparation of chlorothiol formates from thiols and phosgene

Legal Information

TOPO is a registered trademark of Life Technologies

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This Item
2233013461878.14868
assay

≥98.5% (GC)

assay

99%

assay

90%

assay

≥98.0% (GC)

reaction suitability

reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: ligand, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

-

reaction suitability

-

functional group

phosphine oxide

functional group

phosphine

functional group

phosphine oxide

functional group

-

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

-

cation traces

Ca: ≤10 mg/kg, Co: ≤5 mg/kg, Cu: ≤5 mg/kg, K: ≤10 mg/kg, Mn: ≤5 mg/kg, Ni: ≤5 mg/kg, Zn: ≤5 mg/kg, Cd: ≤5 mg/kg, Fe: ≤5 mg/kg, Na: ≤10 mg/kg, Cr: ≤5 mg/kg, Pb: ≤5 mg/kg, Mg: ≤5 mg/kg

cation traces

-

cation traces

-

cation traces

-

bp

201-202 °C/2 mmHg (lit.)

bp

201-202 °C/2 mmHg (lit.)

bp

201-202 °C/2 mmHg (lit.)

bp

212 °C/39.99 Pa


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pictograms

Corrosion

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

446.0 °F - closed cup

flash_point_c

230 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Questions

  1. What are the solvents that can be used to extract magnesium and calcium from Manganese Sulfate in a liquid-liquid extraction application?

    1 answer
    1. The following solvents can be used to extract magnesium and calcium from Manganese Sulfate in a liquid-liquid extraction application:
      DEHPA - 47995-U, p-Cymene - C121452-4L, Aliquat 336 (Methyltrialkylammonium chloride) - 8180790250, and Versatic Acid 10.

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