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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
158534
Trifluoromethanesulfonic acid
reagent grade, 98%, liquid
Synonym(s):
TFMSA, Triflic acid
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Product Name
Trifluoromethanesulfonic acid, reagent grade, 98%
InChI key
ITMCEJHCFYSIIV-UHFFFAOYSA-N
InChI
1S/CHF3O3S/c2-1(3,4)8(5,6)7/h(H,5,6,7)
SMILES string
OS(=O)(=O)C(F)(F)F
grade
reagent grade
vapor density
5.2 (vs air)
vapor pressure
8 mmHg ( 25 °C)
assay
98%
form
liquid
refractive index
n20/D 1.327 (lit.)
Quality Level
pH
0.11
bp
162 °C (lit.)
solubility
water: soluble 1.600 g/L at 20 °C
density
1.696 g/mL at 25 °C (lit.)
functional group
fluoro
triflate
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1 of 4
This Item | 347817 | 8.21166 | 1.08450 |
|---|---|---|---|
| grade reagent grade | grade reagent grade | grade - | grade - |
| assay 98% | assay ≥99% | assay - | assay - |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
| form liquid | form liquid | form liquid | form liquid |
| refractive index n20/D 1.327 (lit.) | refractive index n20/D 1.327 (lit.) | refractive index - | refractive index - |
| vapor density 5.2 (vs air) | vapor density 5.2 (vs air) | vapor density - | vapor density - |
Application
- Friedel-Crafts acylation of aromatic compounds with methyl benzoate.[2]
- Addition reaction of dialkyl disulfides to terminal alkynes.[3]
- Synthesis of a single cyclic tetrasiloxane containing propylammonium trifluoromethanesulfonate and methyl side-chain groups (Am-CyTS).[4]
- Preparation of starting reagents for the synthesis of fluorinated 2,5-substituted 1-ethyl-1H-benzimidazole derivatives.[5]
- Synthesis of aryl triflates,[6] the lactonization of alkenoic acids,[7] and the formation of E-alkenes.[8]
General description
accessory
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
>332.1 °F - Pensky-Martens closed cup
flash_point_c
> 166.7 °C - Pensky-Martens closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Articles
Friedel-Crafts acylation with Lewis acid catalysts forms monoacylated products via electrophilic aromatic substitution of arenes.
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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