172502

Sigma-Aldrich

Thioacetamide

reagent grade, 98%

Synonym(s):
Ethanethioamide, TAA
Linear Formula:
CH3CSNH2
CAS Number:
Molecular Weight:
75.13
Beilstein/REAXYS Number:
506006
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.21

Quality Level

grade

reagent grade

assay

98%

mp

108-112 °C (lit.)

SMILES string

CC(N)=S

InChI

1S/C2H5NS/c1-2(3)4/h1H3,(H2,3,4)

InChI key

YUKQRDCYNOVPGJ-UHFFFAOYSA-N

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General description

Thioacetamide is a thiocarbonyl compound. It undergoes deuterium exchange reaction with D2O to afford N-dideuterated thioacetamide. Infrared spectral investigations of thioacetamide and its deuterated derivative (N-dideuterated thioacetamide) have been reported.

Application

Thioacetamide may be used as a source of sulfur required for the synthesis of CdS nanoparticles in PVA (poly (vinyl alcohol)) solutions. It may be used in the preparation of sulfur precursor stock solution, which was required during the synthesis of CdS quantum dots in PVA-COOH (carboxylic acid functionalized poly(vinyl alcohol)) and EPC (Enzyme-Polymer Conjugate) solutions.
Thioacetamide may be used in the preparation of Sb(TA)2Cl3, a precursor for oxide-free stibnite. The addition of TA during the synthesis of visible-light activated titanium dioxide photocatalysts led to an increase in its photocatalytic activity.

Packaging

25, 100, 500 g in poly bottle

Pictograms

Exclamation markHealth hazard

Signal Word

Danger

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Oxide-free Sb2S3 sensitized solar cells fabricated by spin and heat-treatment of Sb (III)(thioacetamide)2Cl3.
You MS, et al.
Organic Electronics, 21, 155-159 (2015)
Infrared Spectra and Normal Vibrations of Thioamides. II. Thioacetamide.
Suzuki I.
Bulletin of the Chemical Society of Japan, 35(9), 1449-1456 (1962)
Thioacetamide and thiourea impact on visible light activity of TiO2.
Zaleska A, et al.
Applied Catalysis. B, Environmental, 76(1), 1-8 (2007)
Synthesis and characterization of CdS quantum dots with carboxylic-functionalized poly (vinyl alcohol) for bioconjugation
Mansur HS, et al.
Polymer, 52(4), 1045-1054 (2011)
Hong Ling et al.
PloS one, 8(1), e54499-e54499 (2013-01-26)
Considerable evidence has demonstrated that transforming growth factor β (TGF-β) plays a key role in hepatic fibrosis, the final common pathway for a variety of chronic liver diseases leading to liver insufficiency. Although a few studies have reported that blocking...

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