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18122

Sigma-Aldrich

1-Butyl-3-methylimidazolium hexafluorophosphate

greener alternative

for catalysis, ≥98.5% (T)

Synonym(s):
BMIMPF6
Empirical Formula (Hill Notation):
C8H15F6N2P
CAS Number:
Molecular Weight:
284.18
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

grade

for catalysis

assay

≥98.5% (T)

greener alternative product characteristics

Safer Solvents and Auxiliaries
Catalysis
Learn more about the Principles of Green Chemistry.

impurities

≤0.02% water

refractive index

n20/D 1.41

density

1.38 g/mL at 20 °C (lit.)

anion traces

bromide (Br-): ≤10 mg/kg
chloride (Cl-): ≤10 mg/kg
nitrate (NO3-): ≤10 mg/kg
phosphate (PO43-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg

greener alternative category

Aligned

SMILES string

F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1

InChI

1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1

InChI key

IXQYBUDWDLYNMA-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
1-Butyl-3-methylimidazolium hexafluorophosphate is a high-purity ionic liquid (HPIL) with low water and halogen content, which makes it an effective solvent for transition-metal-catalyzed reactions. Some of its other advantageous properties include hydrophobicity and lack of vapor pressure.

Packaging

5, 50 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

More documents

Quotes and Ordering

Temperature-dependent microscopic solvent properties of `dry?and `wet?1-butyl-3-methylimidazolium hexafluorophosphate: correlation with ET (30) and Kamlet?Taft polarity scales
Baker, Sheila N., Gary A. Baker, and Frank V. Bright
Green Chemistry, 4.2, 165-169 (2002)
Thermodynamic properties of 1-butyl-3-methylimidazolium hexafluorophosphate in the ideal gas state
Paulechka, Yauheni U., et al.
Journal of Chemical and Engineering Data, 48.3, 457-462 (2003)
Solvent properties of the 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid
Carda?Broch, S., A. Berthod, and D. W. Armstrong
Analytical and Bioanalytical Chemistry, 375.2, 191-199 (2003)
Olefin Metathesis in the Ionic Liquid 1?Butyl?3?methylimidazolium Hexafluorophosphate Using a Recyclable Ru Catalyst: Remarkable Effect of a Designer Ionic Tag
Yao, Qingwei, and Yiliang Zhang
Angewandte Chemie (International Edition in English), 42.29, 3395-3398 (2003)
The Negishi coupling: an update
Aldrichimica Acta, 38(3), 69-69 (2005)

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