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185698

Barbituric acid

99%, powder, ReagentPlus®

Synonym(s):

2,4,6-Trihydroxypyrimidine, Malonylurea

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Size/SKUAvailabilityPrice
25 g

Available to ship TODAYfromMILWAUKEE

$51.30
100 g

Available to ship TODAYfromMILWAUKEE

$84.20
500 g

Available to ship TODAYfromMILWAUKEE

$169.00

About This Item

Empirical Formula (Hill Notation):
C4H4N2O3
CAS Number:
Molecular Weight:
128.09
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21
EC Number:
200-658-0
MDL number:
Beilstein/REAXYS Number:
120502
Assay:
99%
Form:
powder

$51.30


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Product Name

Barbituric acid, ReagentPlus®, 99%

Quality Segment

product line

ReagentPlus®

assay

99%

form

powder

mp

248-252 °C ((lit.)), 248-252 °C (dec.) (lit.)

SMILES string

[O=C1CC(=O)NC(=O)N1], O=C1CC(=O)NC(=O)N1

InChI

[1S/C4H4N2O3/c7-2-1-3(8)6-4(9)5-2/h1H2,(H2,5,6,7,8,9)], 1S/C4H4N2O3/c7-2-1-3(8)6-4(9)5-2/h1H2,(H2,5,6,7,8,9)

InChI key

[HNYOPLTXPVRDBG-UHFFFAOYSA-N], HNYOPLTXPVRDBG-UHFFFAOYSA-N

General description

Barbituric acid is a useful acid for organic and drug syntheses. Its dihydrate form can be synthesized from barbituric acid via crystallization from aqueous solution. Crystal structure of barbituric acid (in tautomeric form) has been investigated by a three dimensional fourier transform method. Its enol crystal form has been reported to be thermodynamically stable.[1]

Application

Barbituric acid (BA) may be used in the preparation of the corresponding hemiaminals, via chemoselective reduction in the presence of SmI2/H2O reagent.PMID 24123558 It may be used in the preparation of BA- modified conjugated carbon nitride nanosheets.
It may be used to synthesize:
  • 5-ylidenebarbituric acid derivatives via Knoevenagel condensation with aromatic and α,β-conjugated aromatic aldehydes
  • 5-diaminomethylenebarbiturates by reacting with substituted carbodiimides

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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This Item
PHR2865127901911709
description

ReagentPlus®, 99%

description

certified reference material, pharmaceutical secondary standard

description

United States Pharmacopeia (USP) Reference Standard

description

for spectrophotometric det. of cyanide, ≥99.5%

assay

99%

assay

-

assay

-

assay

≥99.5% (HPLC)

Quality Level

200

Quality Level

300

Quality Level

-

Quality Level

100

form

powder

form

solid

form

powder

form

solid

mp

248-252 °C ((lit.)), 248-252 °C (dec.) (lit.)

mp

248-252 °C (dec.) (lit.)

mp

248-252 °C (dec.) (lit.)

mp

248-252 °C (dec.) (lit.)

product line

ReagentPlus®

product line

-

product line

-

product line

-


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Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

302.0 °F - closed cup

flash_point_c

150.00 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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