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242284

Aniline

ACS reagent grade, ≥99.5%, liquid, suitable for analytical testing

Synonym(s):

Aminobenzene, Benzenamine

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Size/SKUAvailabilityPrice
5 mL

Available to ship TODAYfromMILWAUKEE

$41.80
100 mL

Available to ship TODAYfromMILWAUKEE

$52.70
500 mL

Available to ship TODAYfromMILWAUKEE

$126.00
250 mL

Estimated to ship onSeptember 28, 2026fromMILWAUKEE.

$128.00
4 x 100 mL

Available to ship TODAYfromMILWAUKEE

$128.00

About This Item

Linear Formula:
C6H5NH2
CAS Number:
Molecular Weight:
93.13
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39030407
UNSPSC Code:
12352100
EC Number:
200-539-3
MDL number:
Beilstein/REAXYS Number:
605631
Assay:
≥99.5%
Grade:
ACS reagent
Bp:
184 °C (lit.)
Vapor pressure:
0.7 mmHg ( 25 °C)

$41.80


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Product Name

Aniline, ACS reagent, ≥99.5%

material

red polypropylene cap

Quality Segment

grade

ACS reagent

vapor density

3.22 (185 °C, vs air)

vapor pressure

0.7 mmHg ( 25 °C)

assay

≥99.5%

form

liquid

autoignition temp.

1139 °F

expl. lim.

11 %

dilution

(for analytical testing)

impurities

Hydrocarbons, passes test, Nitrobenzene, passes test (lim. ~0.001%), ≤0.01% chlorobenzene

ign. residue

≤0.005%

refractive index

n20/D 1.586 (lit.)

bp

184 °C (lit.)

mp

−6 °C (lit.)

solubility

water: soluble

density

1.022 g/mL at 25 °C (lit.)

storage temp.

room temp

SMILES string

Nc1ccccc1

InChI

1S/C6H7N/c7-6-4-2-1-3-5-6/h1-5H,7H2

InChI key

PAYRUJLWNCNPSJ-UHFFFAOYSA-N

General description

Material darkens in storage to reddish-brown with no loss in purity.

Application

Aniline is an aromatic primary amine that may be used as a reactant in the synthesis of organic intermediates such as 3-chloro-N-phenyl-pyridin-2-amine, (Z)-methyl 3-(phenylamino)but-2-enoate, 2-iodo-N-phenylbenzamide, 2,4-dichloroquinoline and N-(2-propynyl)aniline.

Biochem/physiol Actions

The acute toxicity of aniline involves its activation in vivo to 4-hydroxyaniline and the formation of adducts with hemoglobin. In erythrocytes, this is associated with the release of iron and the accumulation of methemoglobin and the development of hemolytic anemia and inflammation of the spleen. Tumor formation is often observed in the spleen on prolonged administration.

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This Item
51788132934676810
description

ACS reagent, ≥99.5%

description

analytical standard

description

ReagentPlus®, 99%

description

ACS reagent, ≥99.5%

grade

ACS reagent

grade

analytical standard

grade

-

grade

ACS reagent

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

-

assay

≥99.5%

assay

≥99.5% (GC)

assay

99%

assay

≥99.5%

solubility

water: soluble

solubility

-

solubility

water: soluble

solubility

alcohol: soluble(lit.), chloroform: soluble(lit.)

form

liquid

form

-

form

liquid

form

liquid

expl. lim.

11 %

expl. lim.

11 %

expl. lim.

11 %

expl. lim.

2.2-11.5 %, 38 °F


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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1

target_organs

Blood

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

1–4 of 4 Questions  
  1. Does the bottle have to be protected from light, or is the amber bottle sufficient?

    1 answer
    1. An amber bottle is sufficient for storage, and no additional light protection required.

      Helpful?

  2. How is Aniline 5ml (242284-5ml) delivered (glass bottle, other formats) and how can it be stored after initial opening?

    1 answer
    1. This product is packaged in a 10 mL amber glass bottle with a red polypropylene cap. The item may be stored at room temperature before and afer opening.

      Helpful?

  3. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  4. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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