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MilliporeSigma

294772

Decahydronaphthalene, mixture of cis + trans

anhydrous, ≥99%

Synonym(s):

Decalin

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100 ML

$128.00

1 L

$278.00

2 L

$528.00

$128.00


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About This Item

Empirical Formula (Hill Notation):
C10H18
CAS Number:
Molecular Weight:
138.25
UNSPSC Code:
12190000
NACRES:
NA.21
PubChem Substance ID:
EC Number:
202-046-9
Beilstein/REAXYS Number:
878165
MDL number:
Grade:
anhydrous
Assay:
≥99%
Bp:
189-191 °C (lit.)
Vapor pressure:
42 mmHg ( 92 °C)
741 mmHg ( 188 °C)

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Product Name

Decahydronaphthalene, mixture of cis + trans, anhydrous, ≥99%

InChI key

NNBZCPXTIHJBJL-UHFFFAOYSA-N

InChI

1S/C10H18/c1-2-6-10-8-4-3-7-9(10)5-1/h9-10H,1-8H2

SMILES string

C1CCC2CCCCC2C1

grade

anhydrous

vapor density

4.76 (vs air)

vapor pressure

42 mmHg ( 92 °C)
741 mmHg ( 188 °C)

assay

≥99%

form

liquid

autoignition temp.

482 °F

expl. lim.

0.7-4.9 %, 100 °F

impurities

<0.002% water
<0.005% water (100 mL pkg)

refractive index

n20/D 1.474 (lit.)

bp

189-191 °C (lit.)

mp

−125 °C (lit.)

density

0.896 g/mL at 25 °C (lit.)

Quality Level

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1 of 4

This Item
D2518.03101110469
grade

anhydrous

grade

reagent grade

grade

-

grade

-

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

assay

≥99%

assay

98%

assay

≥99% (GC)

assay

99%

form

liquid

form

liquid

form

liquid

form

-

bp

189-191 °C (lit.)

bp

189-191 °C (lit.)

bp

189-191 °C/1013 hPa

bp

193 °C (lit.)

expl. lim.

0.7-4.9 %, 100 °F

expl. lim.

0.7-4.9 %, 100 °F

expl. lim.

0.7-4.9 % (v/v)

expl. lim.

0.7-4.9 %, 100 °F

Application

Decahydronaphthalene, mixture of cis + trans has been used as a liquid phase to study the reaction rate of hydrogenation of cyclohexene in the presence of a Pd–Al/biomorphic carbon catalyst.[1]

Legal Information

Decalin is a trademark of Sigma-Aldrich Co. LLC

related product

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1C

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

134.6 °F - closed cup

flash_point_c

57 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Conformational isomerization of cis-decahydronaphthalene over zeolite catalysts.
Lai WC and Song C.
Catalysis Today, 31(1), 171-181 (1996)
Manuel F Wagenhofer et al.
Science advances, 6(19), eaax5331-eaax5331 (2020-05-20)
Unsupported Ni-Mo sulfides have been hydrothermally synthesized and purified by HCl leaching to remove Ni sulfides. Unblocking of active sites by leaching significantly increases the catalytic activity for dibenzothiophene hydrodesulfurization. The site-specific rates of both direct (hydrogenolytic) and hydrogenative desulfurization
The Densities and Surface Tensions of cis-and trans-Decahydronaphthalene between-30 and 180?1.
Seyer WF and Davenport CH.
Journal of the American Chemical Society, 63(9), 2425-2427 (1941)
Poly (diketopyrrolopyrrole-benzothiadiazole) with Ambipolarity Approaching 100% Equivalency.
Cho S, et al.
Advances in Functional Materials, 21(10), 1910-1916 (2011)
Kinetics of liquid phase cyclohexene hydrogenation on Pd?Al/biomorphic carbon catalysts.
Caza?a F, et al.
Catalysis Today, 249, 127-136 (2015)

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hi, what is the percentage of cis and trans isomers in this solvent?

    1 answer
    1. This product is not tested on a lot to lot basis to determine the cis/trans ratio. However, historical information indicates that these are present in approximately equal proportions.

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