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32222-M

Dichloromethane

puriss. p.a., ACS reagent, reag. ISO, ≥99.9% (GC)

Synonym(s):

methylene chloride, Methylene chloride

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About This Item

Empirical Formula (Hill Notation):
CH2Cl2
CAS Number:
Molecular Weight:
84.93
UNSPSC Code:
12352101
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-838-9
Beilstein/REAXYS Number:
1730800
MDL number:
Assay:
≥99.9% (GC)
Technique(s):
GC/GC: suitable
Bp:
39.8-40 °C (lit.)
Vapor pressure:
24.45 psi ( 55 °C), 6.83 psi ( 20 °C)
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Quality Level

agency

reag. ISO

vapor density

2.9 (vs air)

vapor pressure

24.45 psi ( 55 °C), 6.83 psi ( 20 °C)

grade

ACS reagent, puriss. p.a.

assay

≥99.9% (GC)

form

liquid

autoignition temp.

1223 °F

contains

10-60 ppm amylene as stabilizer

expl. lim.

22 %

technique(s)

GC/GC: suitable

impurities

≤0.00002% free chlorine (Cl), ≤0.0005% formaldehyde, ≤0.001% free acid (as HCl), ≤0.001% non-volatile matter, ≤0.01% chloroform (GC), ≤0.01% tetrachloromethane (GC), ≤0.01% water (Karl Fischer), ≤0.05% ethanol (GC)

refractive index

n20/D 1.4235-1.4245, n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−95 °C (lit.)

density

1.320-1.330 g/L at 20 °C, 1.325 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.5 mg/kg

SMILES string

ClCCl

cation traces

Al: ≤0.5 mg/kg, B: ≤0.02 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.10 ppm, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, K: ≤0.50 ppm, Li: ≤0.10 ppm, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Mo: ≤0.10 ppm, Na: ≤0.50 ppm, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sn: ≤0.1 mg/kg, Sr: ≤0.1 ppm, Zn: ≤0.1 mg/kg

suitability

passes test for reaction against H2SO4

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

General description

Dichloromethane has been tested as a solvent medium for dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. The apparent adsorption constant of the TiO2 loaded activated carbon for dichloromethane was found to be inversely proportional to the quantity of loaded TiO2.

Application

Dichloromethane may be used as a solvent for the preparation of stock solutions of carotenoids.[1] It may be employed as a solvent in the synthesis of polylactide-based (PLA) thin films.[2]

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1 of 1

This Item
320269676853DX0838
assay

≥99.9% (GC)

assay

≥99.5%

assay

≥99.5%

assay

≥99.8% (GC)

technique(s)

GC/GC: suitable

technique(s)

-

technique(s)

-

technique(s)

HPLC: suitable

grade

ACS reagent, puriss. p.a.

grade

ACS reagent

grade

ACS reagent

grade

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

bp

39.8-40 °C (lit.)

bp

39.8-40 °C (lit.)

bp

39.8-40 °C (lit.)

bp

39.8-40 °C (lit.)


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pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable



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R Re et al.
Free radical biology & medicine, 26(9-10), 1231-1237 (1999-06-25)
A method for the screening of antioxidant activity is reported as a decolorization assay applicable to both lipophilic and hydrophilic antioxidants, including flavonoids, hydroxycinnamates, carotenoids, and plasma antioxidants. The pre-formed radical monocation of 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS*+) is generated by oxidation
V Melissinaki et al.
Biofabrication, 3(4), 045005-045005 (2011-09-21)
This study reports on the production of high-resolution 3D structures of polylactide-based materials via multi-photon polymerization and explores their use as neural tissue engineering scaffolds. To achieve this, a liquid polylactide resin was synthesized in house and rendered photocurable via



Global Trade Item Number

SKUGTIN
32222-1L-M04061841186137

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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