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MilliporeSigma

323764

Sigma-Aldrich

1,1′-Diethyl-2,2′-cyanine iodide

97%

Synonym(s):

1-Ethyl-2-[(1-ethyl-2(1H)-quinolinylidene)methyl]quinolinium iodide, Decynium 22, Pseudocyanine iodide, Pseudoisocyanine iodide

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$45.20
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About This Item

Empirical Formula (Hill Notation):
C23H23IN2
CAS Number:
Molecular Weight:
454.35
EC Number:
MDL number:
UNSPSC Code:
12171500
PubChem Substance ID:
NACRES:
NA.47

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Quality Level

assay

97%

form

powder or crystals

mp

273 °C (dec.) (lit.)

λmax

524 nm

ε (extinction coefficient)

≥25000 at 487-495 nm in ethanol

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

[I-].CCN1\C(C=Cc2ccccc12)=C\c3ccc4ccccc4[n+]3CC

InChI

1S/C23H23N2.HI/c1-3-24-20(15-13-18-9-5-7-11-22(18)24)17-21-16-14-19-10-6-8-12-23(19)25(21)4-2;/h5-17H,3-4H2,1-2H3;1H/q+1;/p-1

InChI key

GMYRVMSXMHEDTL-UHFFFAOYSA-M

General description

1,1′-Diethyl-2,2′-cyanine iodide is a quinocyanine dye. This photographic sensitizing dye is mainly used in silver halide photography. 1,1′-Diethyl-2,2′-cyanine iodide dye aggregation in dilute aqueous solution displays red and blue shifted absorption bands.[1]

Application

1,1′-Diethyl-2,2′-cyanine iodide has been used as an absorber in a method to correct the fluorescence excitation-emission matrix (EEM).[2]

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Acute Tox. 4 Dermal - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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The structure of 1, 1'-diethyl-2, 2'-cyanine iodide, a photographic sensitizing dye
Nakatsu K, et al.
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 33(7), 2181-2188 (1977)
Benjamin Dietzek et al.
Physical review letters, 97(25), 258301-258301 (2007-02-07)
We report on adaptive feedback control of photoinduced barrierless isomerization of 1,1'-diethyl-2,2'-cyanine in solution. We compare the effect of different fitness parameters and show that optimal control of the absolute yield of isomerization (photoisomer concentration versus excitation photons) can be
F Martel et al.
Naunyn-Schmiedeberg's archives of pharmacology, 363(1), 40-49 (2001-02-24)
The aim of this work was to characterise the intestinal absorption of organic cations, by testing the possibility of involvement of known members of the amphiphilic solute facilitator (ASF) family in this process. For that purpose, the characteristics of the
Gary C H Mo et al.
Langmuir : the ACS journal of surfaces and colloids, 25(18), 10719-10729 (2009-08-04)
Controlling the self-assembly of molecules into specific structural motifs has important implications for the design of materials with specific optical properties. We report here the results of a correlated confocal fluorescence-atomic force microscopy (AFM) study of pseudoisocyanine iodide (PIC) self-assembly
Yuichi Hashimoto et al.
Journal of colloid and interface science, 311(1), 289-295 (2007-03-21)
We demonstrate a simple method for fabricating a two-dimensional array of microdomes that consist of cyanine dye complexes. Investigation of the morphology and the fluorescence emission of microdomes was carried out before/after annealing. The principal of microdome formation is "dewetting,"

Questions

1–7 of 7 Questions  
  1. What is the solubility of 1,1'-Diethyl-2,2'-cyanine Iodide, Product 323764 in ultrapure water?

    1 answer
    1. The solubility of this product is testing at 10 mg/mL in Dimethyl Formamide : Methanol (1:1). The solubility of this product in water has not been investigated.

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  2. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  3. Where can I find UV-Absorption information for 1,1´-Diethyl-2,2´-cyanine iodide, Product 323764?

    1 answer
    1. UV- Absorption information is found on the Certificate of Analysis of the each lot.

      Helpful?

  4. What can I use to solubilize 1,1´-Diethyl-2,2´-cyanine iodide, Product 323764?

    1 answer
    1. This product is soluble in 1% DMF:Methanol (1:1), yielding a clear, dark solution.

      Helpful?

  5. What are the physical properties of 1,1´-Diethyl-2,2´-cyanine iodide, Product 323764?

    1 answer
    1. This dye is a solid dark red crystals, irritant and light sensitive.

      Helpful?

  6. What is the purity and stability of 1,1´-Diethyl-2,2´-cyanine iodide, Product 323764?

    1 answer
    1. The purity of this product is at least 97% pure by HPLC; it is reported on the Certificate of Analysis of the specific lot. This dye is stable if protected from light (MSDS)

      Helpful?

  7. What is the molecular weight of 1,1´-Diethyl-2,2´-cyanine iodide, Product 323764?

    1 answer
    1. The molecular weight of the product is 454.36 g/mole.

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