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331635

Tetramethylammonium hydroxide solution

25 wt. % in H₂O, solution

Synonym(s):

TMAH solution

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Size/SKUAvailabilityPrice
250 mL

Available to ship TODAYfromMILWAUKEE

$93.70
1 L

Available to ship TODAYfromMILWAUKEE

$221.00

About This Item

Linear Formula:
(CH3)4N(OH)
CAS Number:
Molecular Weight:
91.15
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
3558708
Concentration:
25 wt. % in H2O
Form:
liquid

$93.70


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Product Name

Tetramethylammonium hydroxide solution, 25 wt. % in H2O

vapor pressure

17.5 mmHg ( 20 °C)

Quality Segment

form

liquid

reaction suitability

core: ammonium

concentration

25 wt. % in H2O

refractive index

n20/D 1.3806

pH

>13 (20 °C)

solubility

water: soluble

density

1.016 g/mL at 25 °C

functional group

amine

SMILES string

[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI key

WGTYBPLFGIVFAS-UHFFFAOYSA-M

General description

Tetramethylammonium hydroxide solution is commonly used as a strong base and nucleophilic source in organic synthesis reactions.

Application

Tetramethylammonium hydroxide solution (25 wt.% solution in water) may be used as a base for pH adjustment to obtain hexagonal mesoporous aluminophosphate (TAP).
Tetramethylammonium hydroxide is a quaternary ammonium salt generally used as an anisotropic etchant for silicon due to its high silicon etching rate.

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This Item
79267426318302929
description

25 wt. % in H2O

description

~25% in H2O (1.68 M)

description

ACS reagent

description

35 wt. % in H2O

concentration

25 wt. % in H2O

concentration

~25% in H2O (1.68 M)

concentration

1.0 M±0.02 M in H2O

concentration

35 wt. % in H2O

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

solubility

water: soluble

solubility

-

solubility

-

solubility

-

pH

>13 (20 °C)

pH

-

pH

-

pH

-

refractive index

n20/D 1.3806

refractive index

n20/D 1.395

refractive index

n20/D 1.3497

refractive index

n20/D 1.404


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Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1 Dermal - STOT SE 1

target_organs

Central nervous system, Liver,thymus

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hi Can I ask if this 25% TMAH in water (331635) is ultra pure or analytical grade? Thanks

    1 answer
    1. This product is not tested or recommended for a specific application and is intended for general research use. The material is tested to verify concentration only. Please see the link below to review a sample or lot specific Certificate of Analysis:
      https://www.sigmaaldrich.com/product/sial/331635#product-documentation

      Helpful?

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