33658

Supelco

Picoxystrobin

PESTANAL®, analytical standard

Synonym(s):
Methyl (E)-α-methoxymethylene-2-(3-trifluoromethyl-2-pyridyloxymethyl)phenylacetate
Empirical Formula (Hill Notation):
C18H16F3NO4
CAS Number:
Molecular Weight:
367.32
MDL number:
PubChem Substance ID:
NACRES:
NA.24
Pricing and availability is not currently available.

Quality Level

grade

analytical standard

product line

PESTANAL®

form

neat

CofA

certificate is enclosed in each package

shelf life

limited shelf life, expiry date on the label

application(s)

HPLC: suitable
gas chromatography (GC): suitable

Featured Industry

Agriculture
Environmental

format

neat

SMILES string

CO\C=C(/C(=O)OC)c1ccccc1COc2cccc(n2)C(F)(F)F

InChI

1S/C18H16F3NO4/c1-24-11-14(17(23)25-2)13-7-4-3-6-12(13)10-26-16-9-5-8-15(22-16)18(19,20)21/h3-9,11H,10H2,1-2H3/b14-11-

InChI key

IBSNKSODLGJUMQ-KAMYIIQDSA-N

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Related Categories

General description

Picoxystrobin is classified under the strobulins family of fungicides that exhibit broad range activity against plant pathogenspathogenic fungi.

Application

Picoxystrobin may be used as a reference standard for the determination of picoxystrobin in:
  • Honeybees using acetonitrile-based extraction followed by dispersive solid-phase extraction (d-SPE) cleanup and gas chromatography−tandem quadrupole mass spectrometry (GC−MS/MS).
  • Foodstuffs by liquid chromatography (LC) combined with MS/MS, atmospheric pressure chemical ionization (APCI) and electrospray ionization (ESI).
  • Paddy field water by direct injection using LC coupled with quadrupole-linear ion trap (QqLIT)-MS.
  • Maize by acetonitrile-based extraction with dispersive liquid−liquid microextraction (DLLME) followed by GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

N

Risk Statement

50/53

Safety Statement

60-61

RIDADR

UN 3077 9 / PGIII

WGK Germany

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Stir bar sorptive extraction coupled to liquid chromatography for the analysis of strobilurin fungicides in fruit samples
Campillo N, et al.
Journal of Chromatography A, 1217(27), 4529-4534 (2010)
Marianne Stenrød et al.
PloS one, 8(6), e66989-e66989 (2013-07-03)
There is widespread use of chemical amendments to meet the demands for increased productivity in agriculture. Potentially toxic compounds, single or in mixtures, are added to the soil medium on a regular basis, while the ecotoxicological risk assessment procedures mainly...
Yabing Duan et al.
Pesticide biochemistry and physiology, 153, 95-105 (2019-02-13)
Target leaf spot caused by Corynespora cassiicola is an economically important foliar disease on cucumber. In recent years, this disease has caused a serious problem on greenhouse-cultivated cucumber in China. In this study, to explore the characteristics and possible causes...
Xinzhong Zhang et al.
Journal of the science of food and agriculture, 101(1), 194-204 (2020-07-06)
Picoxystrobin is a new osmotic and systemic broad-spectrum methoxyacrylate fungicide with a good control effect on tea anthracnose, so it has been proposed to spray picoxystrobin before the occurrence and onset of tea anthracnose during tea bud growth in order...
Honglei Zhao et al.
Journal of the science of food and agriculture, 100(14), 5145-5151 (2020-06-11)
Pyraclostrobin and picoxystrobin are two representative pesticides of strobilurins used to treat cucumber downy mildew, which have raised issues of food safety and human health. A new formulation containing these two compounds is being prepared for marketing in China. The...

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