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426318

Tetramethylammonium hydroxide solution

1.0 M±0.02 M in H₂O, solution, ACS reagent grade

Synonym(s):

N,N,N-trimethyl-methanaminium hydroxide, TMAH, TMAOH

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Size/SKUAvailabilityPrice
250 mL

Available to ship TODAYfromMILWAUKEE

$58.80
1 L

Available to ship TODAYfromMILWAUKEE

$179.00
$152.15

About This Item

Linear Formula:
(CH3)4N(OH)
CAS Number:
Molecular Weight:
91.15
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
3558708
Concentration:
1.0 M±0.02 M in H2O
Form:
liquid
Grade:
ACS reagent

$58.80


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Product Name

Tetramethylammonium hydroxide solution, ACS reagent

grade

ACS reagent

Quality Segment

form

liquid

reaction suitability

core: ammonium

concentration

1.0 M±0.02 M in H2O

ign. residue

≤5 ppm

color

APHA: ≤10

refractive index

n20/D 1.3497

bp

100 °C

density

1.005 g/mL at 25 °C

anion traces

chloride (Cl-): ≤0.03%

cation traces

K: ≤2 ppm, Na: ≤2 ppm

functional group

amine

SMILES string

[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI key

WGTYBPLFGIVFAS-UHFFFAOYSA-M

Application

Tetramethylammonium hydroxide solution can be used as:
  • A reagent in the organocatalyzed photoinduced Birch reduction of arenes to 1,4-cyclohexadienes.
  • A catalyst to synthesize 1,2-dihydro-1-arylnaphtho-oxazine-3-one derivatives via one-pot three-component condensation reaction of 2-naphthol, aromatic aldehydes, and urea.
  • A peptizing agent for magnetite nanoparticles to promote repulsive stabilization forces.
  • A template in the hydrothermal synthesis of hierarchical zeolite T aggregates with different sizes.

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This Item
328251331635254533
description

ACS reagent

description

10 wt. % in H2O

description

25 wt. % in H2O

description

1.0 M in H2O

grade

ACS reagent

grade

-

grade

-

grade

-

concentration

1.0 M±0.02 M in H2O

concentration

10 wt. % in H2O

concentration

25 wt. % in H2O

concentration

1.0 M in H2O

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

form

liquid

form

-

form

liquid

form

liquid

bp

100 °C

bp

-

bp

-

bp

-

density

1.005 g/mL at 25 °C

density

1.006 g/mL at 25 °C

density

1.016 g/mL at 25 °C

density

1.012 g/mL at 25 °C


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signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Dermal - STOT SE 2

target_organs

Central nervous system, Liver,thymus

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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