44920

Sigma-Aldrich

Iron(III) acetylacetonate

purum, ≥97.0% (RT)

Synonym(s):
Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate, 2,4-Pentanedione iron(III) derivative
Linear Formula:
Fe(C5H7O2)3
CAS Number:
Molecular Weight:
353.17
Beilstein/REAXYS Number:
4157960
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

grade

purum

assay

≥97.0% (RT)

form

powder

reaction suitability

core: iron
reagent type: catalyst

mp

180-182 °C (dec.) (lit.)
180-190 °C (dec.)

density

5.24 g/mL at 25 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

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Application

MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Other Notes

Catalyst used in Grignard reactions with acid chlorides to give ketones

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Certificate of Analysis

Certificate of Origin

V. Fiandanese et al.
Tetrahedron Letters, 25, 4805-4805 (1984)
C. Cardellicchio et al.
Tetrahedron Letters, 28, 2053-2053 (1987)
Tingting Li et al.
Nanoscale, 7(9), 4171-4178 (2015-02-12)
The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure...
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as...
Michael Challenor et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16780-16787 (2014-10-07)
We report the synthesis, characterisation and evaluation of the in vitro biocompatibility of polymeric nanoparticles with both magnetic and upconverting fluorescent properties. The particles consist of superparamagnetic iron oxide nanoparticles and upconverting NaYF4:Yb,Er nanoparticles co-encapsulated within a poly(glycidyl methacrylate) sphere....

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