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459836

Sigma-Aldrich

Ethyl alcohol, Pure

greener alternative

≥99.5%, anhydrous, 200 proof

Ethyl alcohol, Pure

Synonym(s):

Ethanol, absolute alcohol, non-denatured ethanol

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About This Item

Linear Formula:
CH3CH2OH
CAS Number:
Molecular Weight:
46.07
EC Number:
MDL number:
UNSPSC Code:
15101802
PubChem Substance ID:
NACRES:
NA.21
Grade:
anhydrous
Assay:
≥99.5%
Bp:
78.3 °C
Vapor pressure:
57.26 hPa ( 19.6 °C)

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Product Name

Ethyl alcohol, Pure, 200 proof, anhydrous, ≥99.5%

grade

anhydrous

Quality Level

vapor density

1.59 (vs air)

vapor pressure

57.26 hPa ( 19.6 °C)

assay

≥99.5%

form

liquid

expl. lim.

3.1-27.7 %

availability

not available in (Sales restictions may apply)

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

200 proof

impurities

<0.005% water

evapn. residue

<0.0005%

color

colorless

pH

7 (20 °C, 10 g/L)

bp

78.3 °C

mp

-114 °C

density

0.789 g/mL at 20 °C

greener alternative category

SMILES string

OCC

InChI

1S/C2H6O/c1-2-3/h3H,2H2,1H3

InChI key

LFQSCWFLJHTTHZ-UHFFFAOYSA-N

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1 of 4

This Item
493511493546E7148
grade

anhydrous

grade

ACS spectrophotometric grade

grade

ACS reagent (Traceable to ACS product listing.)

grade

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

assay

≥99.5%

assay

95.0%

assay

≥99.50%

assay

≥95.0%

form

liquid

form

liquid

form

liquid

form

liquid

mp

-114 °C

mp

-114 °C

mp

-114 °C

mp

-114 °C

pH

7 (20 °C, 10 g/L)

pH

-

pH

7.0 (20 °C, 10 g/L)

pH

7.0 (20 °C, 10 g/L)

General description

Pure ethyl alcohol is a non-denatured 200proof ethanol. Ethanol, a primary alcohol, is an important raw material for the synthesis of various compounds. It can be synthesized either from molasses by fermentation or by hydration of ethylene. It acts as a hydrogen source and reaction medium during the transfer hydrogenation of carbonyl compounds in the presence of sodium hydroxide.[1] The impact of ethanol/water fumigation on the performance of diesel engines has been studied.[2] Anhydrous grade solvents show extremely low percentage water and low residue levels.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. Ethanol is environmentally preferable green solvent and thus it aligns with "Safer Solvents and Auxiliaries" and "Use of Renewable Feedstocks". 

Application

Ethanol has been used:
  • as a solvent for lovastatin.[3]
  • as a solvent during the synthesis of (S)-4-hydroxy-2-keto-4-(2′-pyridyl)butyrate.[4]
  • to fix tissue sections on a slide during laser capture microdissection (LCM).[5]

Other Notes

Pure-Pac® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.
Sales restrictions may apply

Legal Information

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

55.4 °F - closed cup

flash_point_c

13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificates of Analysis (COA)

Lot/Batch Number

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J Harry Sweigard et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 28(7), 3171-3182 (2014-03-29)
A defining feature in proliferative retinopathies is the formation of pathological neovessels. In these diseases, the balance between neovessel formation and regression determines blindness, making the modulation of neovessel growth highly desirable. The role of the immune system in these
Sukant Khurana et al.
Chemical senses, 38(4), 315-323 (2013-02-01)
We studied complete dose-response curves for 53 odorants in the third instar larvae of Drosophila melanogaster. All odorants, except one, elicited an attraction response. Some odorants also elicited a decrease from their peak response at higher concentrations. This concentration-dependent decrease
Matthew J Walters et al.
Nature protocols, 2(7), 1825-1830 (2007-07-21)
A procedure for the preparation of optically pure alpha-keto-gamma-hydroxy carboxylic acids through stereospecific aldol addition catalyzed by pyruvate aldolases from the Entner-Doudoroff and the DeLey-Doudoroff glycolytic pathways is described. This highly versatile fragment serves as a precursor for a variety
Sodium hydroxide-catalyzed transfer hydrogenation of carbonyl compounds and nitroarenes using ethanol or isopropanol as both solvent and hydrogen donor.
Wang D, et al.
J. Mol. Catal. A: Chem., 400, 14-21 (2015)
Assessment of a direct injection diesel engine fumigated with ethanol/water mixtures.
Morsy MH.
Energy Conversion and Management , 94, 406-414 (2015)

Articles

Development and validation of a headspace SPME and GC-MS method to determine alcohol content in twenty different Kombucha tea samples.

Protocols

The Extract-N-Amp™ Tissue PCR Kit contains all the reagents needed to rapidly extract and amplify genomic DNA from mouse tails and other animal tissues, buccal swabs, hair shafts, and saliva.

This protocol is designed to allow for high throughput purification of pure genomic DNA from a variety of cultured cells and tissues using the GenElute 96 Well Tissue Genomic DNA Purification Kit.

GenElute™ Bacterial Genomic DNA Kit protocol describes a simple and convenient way for the isolation of pure genomic DNA from bacteria.

The GenElute™ Blood Genomic DNA Kit Protocol provides a simple and convenient way to isolate pure genomic DNA from fresh or aged whole blood.

Related Content

Explore greener solvents including bio-based drop-in replacements, alternative solvents, and ethanol, engineered for sustainable chemistry.

Questions

1–10 of 15 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. What methods do you use for the tests specified on the CoA

    1 answer
    1. The purity of this product is determined by Gas Chromatography (GC) and the moisture content is determined by Karl Fischer. Specific methods are considered proprietary.

      Helpful?

  3. Are all the bottle sizes provided with septum? Or just the 100 ml bottles?

    1 answer
    1. This product is packaged with 'SureSeal' closures which include septa.

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  4. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  5. How do I find the lot number for these reagents? I just recently purchased a 500mL bottle of this. Is the lot umber the same as the "source"?

    1 answer
    1. The lot number may be referred to on the label as the batch or source. The terminology may vary by brand and product type.

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  6. What are the options for drying solvents?

    1 answer
    1. Sigma-Aldrich offers a full range of high-purity solvents with extremely low water levels specifically manufactured for moisture sensitive Organic and Biotech applications.  Sigma-Aldrich also carries various drying agents such as molecular sieves, which are typically compatible with organic solvents.

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  7. What are the options for drying solvents?

    1 answer
    1. Sigma-Aldrich offers a full range of high-purity solvents with extremely low water levels specifically manufactured for moisture sensitive organic and biotech applications.  Sigma-Aldrich also carries various drying agents, which are compatible with organic solvents. For drying ethanol, 3Å molecular sieves are a useful medium for removing any remaining water. For example, we offer these drying agents under such product numbers as 208574 and 208582.

      Helpful?

  8. What is 190 proof and 200 proof ethanol?

    1 answer
    1. All non-denatured ethanol products have a proof associated with the product description. The proof is a measure of the water content of the ethanol portion of the product. The proof is calculated as two times (2 x) the actual ethanol concentration by volume.

      Helpful?

  9. What apparatus do you recommend for HPLC solvent filtration?

    1 answer
    1. The Sigma-Aldrich Vacuum Filtration Assembly gives you all the components you need including: funnel top, fritted glass funnel support, filtration flask, aluminum clamp, and silicone stopper.  The Acrodisc Syringe Filters offer high quality filtration for analytical samples, certified for HPLC to ensure low extractable and available in a broad range of membranes to meet sample compatibility requirements.

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  10. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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1–10 of 15 Questions  

Reviews

Active Filters

  1. Lowell, MA
    • Review 1
    • Votes 2
    5 out of 5 stars.

    Good product. As described by the vendor.

    Product as described. The SureSeal package is extremely useful to main the anhydrous solution.

    Helpful?

  2. 3 Ratings-Only Reviews

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