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471356

Methanesulfonic acid

≥99.0%, liquid

Methanesulfonic acid
1 of 1 reviewers took part in a promotion

Synonym(s):

Mesylic acid, MsOH

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25 mL

Available to ship TODAYfromMILWAUKEE

$66.70
100 mL

Available to ship TODAYfromMILWAUKEE

$78.40
500 mL

Available to ship TODAYfromMILWAUKEE

$150.00
2.5 L

Available to ship TODAYfromMILWAUKEE

$311.00
5 L

Estimated to ship onJune 12, 2026fromMILWAUKEE

$499.00
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$1,900.00

About This Item

Linear Formula:
CH3SO3H
CAS Number:
Molecular Weight:
96.11
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
200-898-6
MDL number:
Beilstein/REAXYS Number:
1446024
Assay:
≥99.0%
Form:
liquid

$66.70


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Product Name

Methanesulfonic acid, ≥99.0%

Quality Level

vapor density

3.3 (vs air), [3.3 (vs air)] (vs air)

vapor pressure

1 mmHg ( 20 °C)

assay

≥99.0%

form

liquid

refractive index

n20/D 1.429 (lit.)

pH range

<1

bp

[167 °C/10 mmHg (lit.)], 167 °C/10 mmHg (lit.)

mp

17-19 °C (lit.)

solubility

water: soluble 1,000 g/L at 20 °C

density

1.481 g/mL at 25 °C (lit.)

functional group

sulfonic acid

SMILES string

O=S(O)(C)=O

InChI

1S/CH4O3S/c1-5(2,3)4/h1H3,(H,2,3,4)

InChI key

AFVFQIVMOAPDHO-UHFFFAOYSA-N

General description

Methanesulfonic acid (MSA) is a strong organic acid. The chemical oxidation of dimetyl sulfide in the atmosphere leads to the formation of MSA in large quantities. MSA undergoes biodegradation by forming CO2 and sulphate. It is considered a green acid as it is less toxic and corrosive in comparison to mineral acids.1 The aqueous MSA solution has been considered a model electrolyte for electrochemical processes.

Application

Methanesulfonic acid may be used:
  • As a catalyst to produce linear alkylbenzenes by the addition reaction between long-chain olefins and benzene.
  • To prepare polyaniline (PANI)/graphene composites with enhanced thermal and electrical properties.
  • As a catalyst for the transformation of glucose/xylose mixtures to levulinic acid and furfural.

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1 of 1

This Item
471348595108.06022
assay

≥99.0%

assay

-

assay

≥99.5% (T)

assay

≥99.0% (acidimetric)

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

form

liquid

form

-

form

liquid

form

liquid

solubility

water: soluble 1,000 g/L at 20 °C

solubility

-

solubility

-

solubility

1000 g/L

mp

17-19 °C (lit.)

mp

-

mp

17-19 °C (lit.)

mp

20 °C

refractive index

n20/D 1.429 (lit.)

refractive index

n20/D 1.416

refractive index

n20/D 1.428-1.430, n20/D 1.429 (lit.)

refractive index

-


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

flash_point_f

372.2 °F - closed cup

flash_point_c

189 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Facile in-situ preparation of polyaniline/graphene nanocomposites using methanesulfonic acid.
Kim DH and Park SY.
Polymer, 55(12), 2928-2935 (2014)
Methane Sulphonic Acid is Green Catalyst in Organic Synthesis.
Kulkarni P.
Orient. J. Chem., 31(1), 447-451 (2015)
Microbial metabolism of methanesulfonic acid.
Kelly DP and Murrell JC.
Archives of Microbiology, 172(6), 341-348 (1999)



Global Trade Item Number

SKUGTIN
471356-20L04022536026213
471356-2.5L04061832359922
471356-25ML04061832359939
471356-100ML04061837548925
471356-500ML04061837548932
471356-5ML04061837548956
471356-5L04061837548949

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the method of synthesis of this? Does it start with methane sulfonyl chloride?

    1 answer
    1. Methods of preparation for this product are considered proprietary.

      Helpful?

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