52862

Supelco

Sodium 1-hexanesulfonate monohydrate

suitable for ion pair chromatography, LiChropur, ≥99.0% (T)

Synonym(s):
1-Hexanesulfonic acid sodium salt monohydrate
Linear Formula:
CH3(CH2)4CH2SO3Na · H2O
CAS Number:
Molecular Weight:
206.24
Beilstein/REAXYS Number:
3727014
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NB.21
Pricing and availability is not currently available.

Quality Level

description

anionic

assay

≥99.0% (T)

quality

LiChropur

mol wt

206.24 g/mol

application(s)

HPLC: suitable
ion pair chromatography: suitable

λ

10 % in H2O

UV absorption

λ: 210 nm Amax: 0.1
λ: 220 nm Amax: 0.06
λ: 230 nm Amax: 0.04
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02

suitability

corresponds to standard for RP gradient test
corresponds to standard for filter test

SMILES string

O.Na+.CCCCCCS(O-)(=O)=O

InChI

1S/C6H14O3S.Na.H2O/c1-2-3-4-5-6-10(7,8)9;;/h2-6H2,1H3,(H,7,8,9);;1H2/q;+1;/p-1

InChI key

CLCGFJYKZGFGSQ-UHFFFAOYSA-M

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Application

Sodium 1-hexanesulfonate monohydrate has been used as an ion-pairing reagent during LC-ICPMS (Liquid chromatography- Inductively coupled plasma mass spectrometry (ICP-MS)), done for rapid separation of arsenic species.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Rapid arsenic speciation using ion pair LC-ICPMS with a monolithic silica column reveals increased urinary DMA excretion after ingestion of rice
Pearson, Gareth F., et al.
Journal of Analytical Atomic Spectrometry, 22 (4), 361-369 (2007)
Kirti S Niralwad et al.
Ultrasonics sonochemistry, 17(5), 760-763 (2010-03-17)
1-Hexanesulphonic acid sodium salt was found to be an efficient catalyst for the green synthesis of alpha-aminophosphonates by the coupling of aldehydes/ketone, an amine and triethyl phosphite under ultrasound irradiation at ambient temperature for appropriate time to furnish the desired...
Philip Zakaria et al.
Electrophoresis, 23(17), 2821-2832 (2002-09-11)
The separation of a series of aromatic carboxylic acids, sulfonates and opiates using electrokinetic chromatography employing a mixture of the soluble cationic polymer poly(diallydimethylammonium chloride) (PDDAC) and the amphiphilic anion hexanesulfonate as pseudostationary phases is described. In this system, the...
A R Calhoun et al.
Journal of colloid and interface science, 309(2), 505-510 (2007-03-03)
Measurements have been made to determine the solubility of ethane, C2H6, in aqueous solutions of four different surfactants of the linear alkanesulfonate class at 25 degrees C. The surfactants, sodium 1-pentanesulfonate, sodium 1-hexanesulfonate, sodium 1-heptanesulfonate, and sodium 1-octanesulfonate, all share...

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