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64870

Sigma-Aldrich

4-Methoxybenzyl chloride

purum, ≥97.0% (GC)

Synonym(s):
4-(Chloromethyl)anisole
Linear Formula:
CH3OC6H4CH2Cl
CAS Number:
Molecular Weight:
156.61
Beilstein:
606667
EC Number:
MDL number:
PubChem Substance ID:

grade

purum

assay

≥97.0% (GC)

contains

1% potassium carbonate as stabilizer

impurities

bottom sediment (K2CO3)

refractive index

n20/D 1.548 (lit.)
n20/D 1.548

bp

117-118 °C/14 mmHg (lit.)

mp

−1 °C (lit.)

density

1.155 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

COc1ccc(CCl)cc1

InChI

1S/C8H9ClO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6H2,1H3

InChI key

MOHYOXXOKFQHDC-UHFFFAOYSA-N

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Other Notes

Protecting group reagent for alcohols; the ethers are cleaved hydrogenolytically as well as oxidatively with DDQ or ceric ammonium nitrate, CAN

Certificate of Analysis

Certificate of Origin

B.T. Golding
Chemistry & Industry, 617-617 (1988)
K. Horita et al.
Tetrahedron, 42, 3021-3021 (1986)

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