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Supelco

Ethyl acrylate

analytical standard

Synonym(s):

Acrylic acid ethyl ester

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About This Item

Linear Formula:
CH2=CHCOOC2H5
CAS Number:
Molecular Weight:
100.12
Beilstein/REAXYS Number:
773866
EC Number:
MDL number:
UNSPSC Code:
85151701
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

3.5 (vs air)

vapor pressure

31 mmHg ( 20 °C)

assay

≥99.5% (GC)

autoignition temp.

721 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.002% hydroquinone monomethyl ether as stabilizer

expl. lim.

12.1 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.406 (lit.)
n20/D 1.406

bp

99 °C (lit.)

mp

−71 °C (lit.)

density

0.921 g/mL at 20 °C
0.918 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care
petroleum

format

neat

SMILES string

CCOC(=O)C=C

InChI

1S/C5H8O2/c1-3-5(6)7-4-2/h3H,1,4H2,2H3

InChI key

JIGUQPWFLRLWPJ-UHFFFAOYSA-N

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General description

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Find all available reference materials for compounds listed in 10/2011 here

Application

Ethyl acrylate can undergo anionic polymerization upon initiation by tetrabutylammonium azide in the presence of alkylaluminum bisphenoxides in toluene to yield azide-end poly(ethyl acrylate) (PEA).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms

FlameSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 2

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificates of Analysis (COA)

Lot/Batch Number

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Supelco

43348

Farnesol

Anionic polymerization of ethyl acrylate initiated by tetrabutylammonium azide: direct synthesis of end-clickable polyacrylate
Kataoka Y, et al.
Polym. Chem. (2017)
Anna E V Hagström et al.
Biotechnology and bioengineering, 102(3), 693-699 (2008-09-30)
An OH-functional polyester has been acrylated via transesterification of ethyl acrylate, catalyzed by Candida antarctica lipase B (CalB) in two different preparations: Novozym 435 and immobilized on Accurel MP1000. The batch process resulted in incomplete acrylation as well as severe
M Monier et al.
Journal of hazardous materials, 176(1-3), 348-355 (2009-12-08)
The graft copolymerization of ethyl acrylate (EA) onto natural wool fibers initiated by potassium persulphate and Mohr's salt redox initiator system in limited aqueous medium was carried out in heterogeneous media. Ester groups of the grafted copolymers were partially converted
M Shahjahan Kabir et al.
The Journal of organic chemistry, 77(1), 300-310 (2011-11-15)
The stereospecific synthesis of aryloxy and amino substituted E- and Z-ethyl-3-acrylates is of interest because of their potential in the polymer industry and in medicinal chemistry. During work on a copper-catalyzed cross-coupling reaction of ethyl (E)- and (Z)-3-iodoacrylates with phenols
Junliang Wu et al.
Journal of the American Chemical Society, 131(39), 13888-13889 (2009-09-15)
The direct cross-coupling of quinoline-N-oxides with olefin derivatives has been realized using palladium acetate as the catalyst in the absence of external ligand and oxidant to give the corresponding 2-alkenylated quinolines and 1-alkenylated isoquinolines chemo- and regioselectively in 27-95% yield.

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