76130

Supelco

Ethyl acrylate

analytical standard

Synonym(s):
Acrylic acid ethyl ester
Linear Formula:
CH2=CHCOOC2H5
CAS Number:
Molecular Weight:
100.12
Beilstein/REAXYS Number:
773866
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.24
Pricing and availability is not currently available.

Quality Level

grade

analytical standard

vapor density

3.5 (vs air)

vapor pressure

31 mmHg ( 20 °C)

assay

≥99.5% (GC)

form

neat

CofA

certificate is enclosed in each package

autoignition temp.

721 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.002% hydroquinone monomethyl ether as stabilizer

expl. lim.

12.1 %

application(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.406 (lit.)
n20/D 1.406

bp

99 °C (lit.)

mp

−71 °C (lit.)

density

0.921 g/mL at 20 °C
0.918 g/mL at 25 °C (lit.)

Featured Industry

Cleaning Products
Cosmetics
Environmental
Flavors and Fragrances
Food and Beverages
Personal Care
Petroleum

format

neat

SMILES string

CCOC(=O)C=C

InChI

1S/C5H8O2/c1-3-5(6)7-4-2/h3H,1,4H2,2H3

InChI key

JIGUQPWFLRLWPJ-UHFFFAOYSA-N

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Ethyl acrylate can undergo anionic polymerization upon initiation by tetrabutylammonium azide in the presence of alkylaluminum bisphenoxides in toluene to yield azide-end poly(ethyl acrylate) (PEA).

Pictograms

FlameSkull and crossbones

Signal Word

Danger

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

F,Xn

Risk Statement

11-20/21/22-36/37/38-43

Safety Statement

9-16-33-36/37

RIDADR

UN 1917 3 / PGII

WGK Germany

WGK 2

Flash Point(F)

48.2 °F - closed cup

Flash Point(C)

9 °C - closed cup

Anionic polymerization of ethyl acrylate initiated by tetrabutylammonium azide: direct synthesis of end-clickable polyacrylate
Kataoka Y, et al.
Polym. Chem. (2017)
M Shahjahan Kabir et al.
The Journal of organic chemistry, 77(1), 300-310 (2011-11-15)
The stereospecific synthesis of aryloxy and amino substituted E- and Z-ethyl-3-acrylates is of interest because of their potential in the polymer industry and in medicinal chemistry. During work on a copper-catalyzed cross-coupling reaction of ethyl (E)- and (Z)-3-iodoacrylates with phenols...
Aaron Mark Drucker et al.
Dermatitis : contact, atopic, occupational, drug, 22(2), 98-101 (2011-04-21)
Acrylates are present in a wide variety of products and cause occupational and non-occupational allergic contact dermatitis. There is no clear guidance from the literature as to which allergens should be used for patch-test screening for acrylates. To characterize patients...
Junliang Wu et al.
Journal of the American Chemical Society, 131(39), 13888-13889 (2009-09-15)
The direct cross-coupling of quinoline-N-oxides with olefin derivatives has been realized using palladium acetate as the catalyst in the absence of external ligand and oxidant to give the corresponding 2-alkenylated quinolines and 1-alkenylated isoquinolines chemo- and regioselectively in 27-95% yield....
Jiaan Shao et al.
Organic letters, 14(21), 5452-5455 (2012-10-26)
Palladium-catalyzed C-H functionalization using guanidine as the directing group was achieved under mild reaction conditions. Various guanidine derivatives were produced in moderate to good yields by using simple unactivated arenes or ethyl acrylate as the source of arylation or olefination...

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