MilliporeSigma
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82762

Supelco

Methanol

analytical standard

Synonym(s):
Methyl alcohol
Linear Formula:
CH3OH
CAS Number:
Molecular Weight:
32.04
Beilstein:
1098229
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

1.11 (vs air)

vapor pressure

410 mmHg ( 50 °C)
97.68 mmHg ( 20 °C)

Assay

≥99.9% (GC)

form

liquid

autoignition temp.

725 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

36 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.329 (lit.)
n20/D 1.329

bp

64.7 °C (lit.)

mp

−98 °C (lit.)

density

0.791 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

SMILES string

CO

InChI

1S/CH4O/c1-2/h2H,1H3

InChI key

OKKJLVBELUTLKV-UHFFFAOYSA-N

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This Item
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Methanol analytical standard

Supelco

82762

Methanol

Ethylene glycol analytical standard

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85978

Ethylene glycol

Dimethyl sulfoxide analytical standard

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94563

Dimethyl sulfoxide

1-Methyl-2-pyrrolidinone analytical standard

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78769

1-Methyl-2-pyrrolidinone

assay

≥99.9% (GC)

assay

≥99.9% (GC)

assay

≥99.95% (GC)

assay

≥99.9% (GC)

form

liquid

form

-

form

-

form

-

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

environmental

application(s)

environmental

application(s)

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

General description

Methanol is a primary alcohol, which is commercially manufactured from methane. It can also be obtained via pyrolysis of wood. It can find applications in organic synthesis reactions, as a highly polar solvent.
This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Application

Methanol may be used as an analytical standard for the determination of the analyte content in biodiesel, wine, and biological fluids by gas chromatography (GC) technique. It can also be used as a solvent/eluent for the preparation of various standard solutions and the extraction of analytes for their subsequent determination using analytical techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

49.5 °F - closed cup

Flash Point(C)

9.7 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (Example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

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Gas chromatographic analysis of methyl formate and application in methanol poisoning cases
Fraser AD and MacNeil W
Journal of Analytical Toxicology, 13(2), 73-76 (1989)
Methanol Fuel Cell Systems: Advancing Towards Commercialization (2016)
The calculation of retention and selectivity in reversed-phase liquid chromatography II. Methanol-water eluents
Galushko SV
Chromatographia, 36(1), 39-42 (1993)
Determination of di-and tributyltin in sediment and microbial biofilms using acidified methanol extraction, sodium borohydride derivatization and gas chromatography with flame photometric detection
Matthias CL, et al.
International Journal of Environmental Analytical Chemistry, 35(2), 61-68 (1989)
Chromatography separation, 1H NMR analysis and bioautography screening of methanol extract of Excoecaria agallocha L. from Bhitarkanika, Orissa, India
Patra JK, et al.
Asian Pacific Journal of Tropical Biomedicine, 2(1), S50-S56 (2012)

Articles

The Utility of Headspace Grade Solvents for the Analysis of Organic Volatile Impurities

The Utility of Headspace Grade Solvents for the Analysis of Organic Volatile Impurities

Protocols

GC Analysis of Fermentation Compounds on a Packed Column (6.6% Carbowax® 20M on 80/120 Carbopack™ B AW)

Separation of Acetone; Acetic acid; Propionic acid; Ethyl butyrate; Ethanol; Isoamyl acetate; Isobutyric acid; 3-Methyl-2-butanol; Methyl acetate; 1-Propanol; Acetal, ≥98%, FG; 2-Methyl-1-pentanol; Butyl acetate; Ethyl propionate; 3-Pentanol; 2-Pentanol, 98%; Ethyl isobutyrate; Isobutyl acetate; Acetaldehyde; Furfural; Butyric acid; Methanol; Ethyl acetate

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service