86879

Supelco

Tetrabutylammonium hexafluorophosphate

for electrochemical analysis, ≥99.0%

Linear Formula:
(CH3CH2CH2CH2)4N(PF6)
CAS Number:
Molecular Weight:
387.43
Beilstein/REAXYS Number:
4056584
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NB.61

grade

for electrochemical analysis

Quality Level

assay

≥99.0% (CHN)
≥99.0%

mp

244-246 °C (lit.)

solubility

acetonitrile: 0.1 g/mL, clear, colorless

SMILES string

F[P-](F)(F)(F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1

InChI key

BKBKEFQIOUYLBC-UHFFFAOYSA-N

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General description

Tetrabutylammonium hexafluorophosphate (TBAHFP) is a quaternary ammonium salt, mainly used as electrolyte. It is soluble in solvents like liquid sulphur dioxide and methylene chloride.
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Application

TBAHFP has been used in the preparation of poly-3-methylthiophene combined with γ-cyclodextrin (P3MT/γ-CD) electrode using electrochemical synthesis method.

Other Notes

Supporting electrolyte soluble in organic solvents which is very stable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

A novel electrochemical synthesis of poly-3-methylthiophene-gamma-cyclodextrin film Application for the analysis of chlorpromazine and some neurotransmitters.
Bouchta D
Biosensors And Bioelectronics, 20(11), 2228-2235 (2005)
M.M. Baizer
Organic Electrochemistry null
null
Sonia Bruña et al.
Dalton transactions (Cambridge, England : 2003), 43(35), 13187-13195 (2014-07-17)
Reaction of Fe3(CO)12 with 1,2-dithiolene HSC6H2Cl2SH affords a mixture of complexes [Fe2(CO)6(μ-SC6H2Cl2S)] 1, [Fe2(SC6H2Cl2S)4] 2 and [Fe3(CO)7(μ3-SC6H2Cl2S)2] 3. In the course of the reaction the trimetallic cluster 3 is first formed and then converted into the known dinuclear compound 1...
Ting-Ting Li et al.
ChemSusChem, 12(11), 2402-2408 (2019-05-10)
A RuII complex [Ru(PO3 Et2 -ph-tpy)(6-mbpy)(NCCH3 )]2+ [PO3 Et2 -ph-tpy=diethyl(4-[(2,2':6',2''-terpyridin)-4'-yl]phenyl)phosphonate; 6-mbpy=6-methyl-2,2'-bipyridine] is explored as a molecular catalyst for electrocatalytic CO2 reduction in both a homogeneous solution and, as a phosphonated derivative, on nanocrystalline-TiO2 surfaces. In CH3 CN, the complex acts...

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