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86879

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Tetrabutylammonium hexafluorophosphate

for electrochemical analysis, ≥99.0%

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Linear Formula:
(CH3CH2CH2CH2)4N(PF6)
CAS Number:
Molecular Weight:
387.43
Beilstein:
4056584
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NB.61

grade

for electrochemical analysis

Quality Level

Assay

≥99.0% (CHN)
≥99.0%

form

solid

mp

244-246 °C (lit.)

solubility

acetonitrile: 0.1 g/mL, clear, colorless

SMILES string

F[P-](F)(F)(F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1

InChI key

BKBKEFQIOUYLBC-UHFFFAOYSA-N

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1 of 4

This Item
8687486896155837
form

solid

form

powder

form

crystals

form

solid

mp

244-246 °C (lit.)

mp

244-246 °C (lit.)

mp

155-161 °C (lit.), 159-162 °C

mp

169-171 °C (lit.)

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

grade

for electrochemical analysis

grade

-

grade

for electrochemical analysis

grade

-

solubility

acetonitrile: 0.1 g/mL, clear, colorless

solubility

-

solubility

methanol: 0.1 g/mL, clear, colorless

solubility

-

General description

Tetrabutylammonium hexafluorophosphate (TBAHFP) is a quaternary ammonium salt, mainly used as electrolyte. It is soluble in solvents like liquid sulphur dioxide and methylene chloride.
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Application

TBAHFP has been used in the preparation of poly-3-methylthiophene combined with γ-cyclodextrin (P3MT/γ-CD) electrode using electrochemical synthesis method.

Other Notes

Supporting electrolyte soluble in organic solvents which is very stable

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Md Khairul Hoque et al.
Frontiers in chemistry, 8, 593932-593932 (2020-11-27)
Nitrogen-free amorphous carbon thin films prepared via sputtering followed by graphitization, were used as precursor materials for the creation of N-doped carbon electrodes with varying degrees of amorphization. Incorporation of N-sites was achieved via nitrogen plasma treatments which resulted in
A novel electrochemical synthesis of poly-3-methylthiophene-gamma-cyclodextrin film Application for the analysis of chlorpromazine and some neurotransmitters.
Bouchta D
Biosensors And Bioelectronics, 20(11), 2228-2235 (2005)
M.M. Baizer
Organic Electrochemistry null
Sonia Bruña et al.
Dalton transactions (Cambridge, England : 2003), 43(35), 13187-13195 (2014-07-17)
Reaction of Fe3(CO)12 with 1,2-dithiolene HSC6H2Cl2SH affords a mixture of complexes [Fe2(CO)6(μ-SC6H2Cl2S)] 1, [Fe2(SC6H2Cl2S)4] 2 and [Fe3(CO)7(μ3-SC6H2Cl2S)2] 3. In the course of the reaction the trimetallic cluster 3 is first formed and then converted into the known dinuclear compound 1
Ting-Ting Li et al.
ChemSusChem, 12(11), 2402-2408 (2019-05-10)
A RuII complex [Ru(PO3 Et2 -ph-tpy)(6-mbpy)(NCCH3 )]2+ [PO3 Et2 -ph-tpy=diethyl(4-[(2,2':6',2''-terpyridin)-4'-yl]phenyl)phosphonate; 6-mbpy=6-methyl-2,2'-bipyridine] is explored as a molecular catalyst for electrocatalytic CO2 reduction in both a homogeneous solution and, as a phosphonated derivative, on nanocrystalline-TiO2 surfaces. In CH3 CN, the complex acts

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