87299

Supelco

Tetrahexylammonium hydrogensulfate

suitable for ion pair chromatography, LiChropur, ≥99.0% (T)

Linear Formula:
CH3(CH2)54N(HSO4)
CAS Number:
Molecular Weight:
451.75
Beilstein/REAXYS Number:
4629729
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NB.21
Pricing and availability is not currently available.

Quality Level

description

cationic

assay

≥99.0% (T)

quality

LiChropur

application(s)

HPLC: suitable
ion pair chromatography: suitable

mp

98-100 °C (lit.)
99-102 °C

λ

10 % in acetonitrile

UV absorption

λ: 210 nm Amax: 0.10
λ: 220 nm Amax: 0.04
λ: 230 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02

suitability

corresponds to standard for RP gradient test
corresponds to standard for filter test

SMILES string

OS(O-)(=O)=O.CCCCCCN+(CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C24H52N.H2O4S/c1-5-9-13-17-21-25(22-18-14-10-6-2,23-19-15-11-7-3)24-20-16-12-8-4;1-5(2,3)4/h5-24H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI key

RULHPTADXJPDSN-UHFFFAOYSA-M

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General description

Tetrahexylammonium hydrogensulfate is a quaternary ammonium salt mainly used as an electrolyte.

Application

Tetrahexylammonium hydrogensulfate may have been used as a phase-transfer catalyst during catalysis analysis of benzylic halide to carboxylic acid.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xi

Risk Statement

36/37/38

Safety Statement

26-36

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Selective phase transfer and palladium (0)-catalyzed carbonylation, carbalkoxylation, and reduction reactions.
Alper, Howard, Khaled Hashem, and Josef Heveling.
Organometallics, 1.6, 775-778 (1982)
K M Sunasara et al.
Biotechnology progress, 17(5), 897-906 (2001-10-06)
This work investigates the utility of RPLC displacement chromatography for the purification of recombinant brain derived neurotrophic factor (rHu-BDNF) from its variants and E. coli. protein (ECP) impurities. The closely associated variants (six in total) differ by one amino acid...
L Zhang et al.
The Journal of pharmacology and experimental therapeutics, 288(3), 1192-1198 (1999-02-23)
Polyspecific organic cation transporters in epithelia play an important role in the elimination of many endogenous bioactive amines and therapeutically important drugs. Recently, the first human organic cation transporter (hOCT1) was cloned from liver. The purpose of the current study...
L G Sayers et al.
Biochimica et biophysica acta, 1152(1), 177-183 (1993-10-10)
In this study we show that the potassium-channel blocker tetrahexyl ammonium chloride (THA+) is able to inhibit inositol 1,4,5-trisphosphate (InsP3)-induced calcium release in an apparently biphasic fashion with a IC50 of 3 microM. This inhibition was not alleviated by valinomycin...
A F Hofmann
Journal of lipid research, 8(1), 55-58 (1967-01-01)
Ethyl acetate or chloroform solutions of tetraheptylammonium chloride, an oil-soluble quaternary amine, quantitatively extract polar, anionic lipids such as steroid or bile salt conjugates from aqueous solution by a process of anion exchange.

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