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89456

Supelco

4,4′,4″,4″′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid)

for spectrophotometric det. of transition metals, ≥95.0%

All Photos(2)
Synonym(s):
meso-Tetraphenylporphine-4,4′,4″,4″′-tetrasulfonic acid
Empirical Formula (Hill Notation):
C44H30N4O12S4
CAS Number:
35218-75-8
Molecular Weight:
934.99
Beilstein:
4227566
MDL number:
MFCD00070632
PubChem Substance ID:
329769738
NACRES:
NA.21

Quality Level

100

Assay

≥95.0% (HPLC)
≥95.0%

form

powder

quality

for spectrophotometric det. of transition metals

technique(s)

UV/Vis spectroscopy: suitable

impurities

~9% water

SMILES string

OS(=O)(=O)c1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(cc4)S(O)(=O)=O)c5ccc([nH]5)c(-c6ccc(cc6)S(O)(=O)=O)c7ccc(n7)c(-c8ccc(cc8)S(O)(=O)=O)c9ccc2[nH]9

InChI

1S/C44H30N4O12S4/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57/h1-24,45,48H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

PBHVCRIXMXQXPD-LWQDQPMZSA-N

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This Item
37907738940496738
4,4′,4″,4″′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid) for spectrophotometric det. of transition metals, ≥95.0%

Supelco

89456

4,4′,4″,4″′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid)

4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid) Dye content 75 %

Sigma-Aldrich

379077

4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)

5,10,15,20-Tetraphenyl-21H, 23H-porphine-p,p′,p,p′′′-tetrasulfonic acid tetrasodium hydrate

Sigma-Aldrich

389404

5,10,15,20-Tetraphenyl-21H, 23H-porphine-p,p′,p,p′′′-tetrasulfonic acid tetrasodium hydrate

(R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl ≥95.0% (H-NMR)

Sigma-Aldrich

96738

(R)-(+)-5,5′-Dichloro-2,2′-bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl

form

powder

form

powder

form

powder, crystals or chunks

form

crystals

Quality Level

100

Quality Level

-

Quality Level

100

Quality Level

-

quality

for spectrophotometric det. of transition metals

quality

-

quality

-

quality

-

technique(s)

UV/Vis spectroscopy: suitable

technique(s)

-

technique(s)

-

technique(s)

-

impurities

~9% water

impurities

-

impurities

-

impurities

-

Application

4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid) [tetrasodium salt hydrate, TPPS] has been used in preparing Co–Al LDH/Fe(III)-TPPS film modified electrode; for demonstrating reversible redox peak attribution to Co(III)/Co(II), with iron(III) porphyrin; making it mediator for electron transfer.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Analysis Note

max. Absorption (in Methanol): 412-416 nm

Other Notes

Reagent for the spectrophotometric determination of ultra trace amounts of transition metals; determination by capillary zone electrophoresis

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315 - H319 - H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Kalivarathan Divakar et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 27(1), 101-103 (2011-01-15)
Protein identification in polyacrylamide gel electrophoresis (PAGE) requires post-electrophoretic steps like fixing, staining and destaining of the gel, which are time-consuming and cumbersome. We have developed a method for direct visualization of protein bands in PAGE using tetrakis(4-sulfonato phenyl)porphyrin (TPPS)
E Collini
Physical chemistry chemical physics : PCCP, 14(11), 3725-3736 (2012-02-14)
In the search of new materials characterized by high two-photon absorption (TPA) efficiency, many efforts have been devoted to design chromophores with enhanced TPA responses progressively moving from linear chromophores such as dipoles and quadrupoles toward multimeric complex molecular architectures.
Layer-by-layer assembly of porphyrin/layered double hydroxide ultrathin film and its electrocatalytic behavior for H 2 O 2.
Shao, Mingfei, et al.
Electrochemical Communications, 12.8, 1077-1080 (2010)
Ali Farajtabar et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 213-220 (2011-09-17)
The solvatochromic properties of the free base and the protonated 5, 10, 15, 20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) were studied in pure water, methanol, ethanol (protic solvents), dimethylsulfoxide, DMSO, (non-protic solvent), and their corresponding aqueous-organic binary mixed solvents. The correlation of the empirical
Kunio Kawamura et al.
Talanta, 84(5), 1318-1322 (2011-06-07)
A new type of flow injection analysis (FIA) system combined with an extremely high temperature reactor, namely hydrothermal flow injection analysis (HT-FIA), has been successfully constructed for the first time. Fundamental characteristics of HT-FIA system, such as limit temperature, pressure
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