Skip to Content
MilliporeSigma

Skip To

90964

Hydrogen chloride solution

3 M in methanol, derivatization grade (GC derivatization), LiChropur

Synonym(s):

Methanolic HCl

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Size/SKUAvailabilityPrice
10 x 1 mL

Available to ship TODAYfromMILWAUKEE

$91.20
100 mL

Available to ship TODAYfromMILWAUKEE

$97.30
500 mL

Available to ship TODAYfromMILWAUKEE

$351.00

About This Item

Empirical Formula (Hill Notation):
HCl
CAS Number:
Molecular Weight:
36.46
UNSPSC Code:
12352301
NACRES:
NA.05
MDL number:
Concentration:
3 M in methanol
Form:
liquid
Grade:
derivatization grade (GC derivatization)

$91.20


Available to ship TODAYDetails


Request a Custom Order
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist


grade

derivatization grade (GC derivatization)

Quality Segment

product line

LiChropur

form

liquid

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

concentration

3 M in methanol

technique(s)

gas chromatography (GC): suitable

density

0.871-0.881 g/mL at 20 °C

shipped in

dry ice

storage temp.

−20°C

SMILES string

Cl

InChI

1S/ClH/h1H

InChI key

VEXZGXHMUGYJMC-UHFFFAOYSA-N

General description

Methanolic HCl (hydrogen chloride in methanol) is particularly useful for preparing methyl esters of volatile (short chain) fatty acids. Fatty acids are esterified by heating them with an anhydrous alcohol (e.g., methanol) in the presence of an acidic catalyst (e.g., HCl) in a sealed vessel at a high temperature for a short time. In the reaction, a fatty acid molecule and an alcohol molecule are joined, with the release of a water molecule. The derivatives can be quickly and easily recovered, quantitatively, from the reaction medium.

Application

Learn more in the Product Information
Suitable for derivatization of corticosteroids, estrogens, fatty acids, hop and beer bitter acids, lipids and formic and acetic acid (in cigarette smoke).

Features and Benefits

  • Derivatization of fatty acids, particularly volatile (short chain) fatty acids
  • Clean reaction (no side reaction) with volatile by-products
  • Provides clean, fast, quantitative derivatization

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
076071.13134455180
concentration

3 M in methanol

concentration

0.45-0.55 M in methanol, 0.5 M in methanol

concentration

3.571 M

concentration

1.90-2.20 M (with NaOH, titration), 2.0 M in diethyl ether

grade

derivatization grade (GC derivatization)

grade

derivatization grade ((GC derivatization))

grade

-

grade

-

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

form

liquid

form

liquid

form

liquid

form

liquid

storage temp.

−20°C

storage temp.

2-8°C

storage temp.

15-25°C

storage temp.

2-8°C

density

0.871-0.881 g/mL at 20 °C

density

0.801-0.812 g/mL at 20 °C

density

1.06 g/cm3 at 20 °C

density

0.747 g/mL at 25 °C


Still not finding the right product?

Explore all of our products under Hydrogen chloride solution


signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 1 - STOT SE 3

target_organs

Eyes,Central nervous system, Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

49.5 °F - closed cup

flash_point_c

9.7 °C - closed cup



Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library



Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters