The volumetric method used for analysis was titration with HClO4.
E26266
Ethylenediamine
≥99%, liquid, ReagentPlus®
Ethylenediamine
Synonym(s):
1,2-Diaminoethane
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| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 mL | Available to ship TODAYfromMILWAUKEE | $45.40 | |
| 100 mL | Available to ship TODAYfromMILWAUKEE | $58.00 | |
| 1 L | Available to ship TODAYfromMILWAUKEE | $76.30 | |
| 2.5 L | Available to ship TODAYfromMILWAUKEE | $169.00 | |
| 4 x 100 mL | Available to ship TODAYfromMILWAUKEE | $186.00 $139.50 |
About This Item
Linear Formula:
NH2CH2CH2NH2
CAS Number:
Molecular Weight:
60.10
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39030201
UNSPSC Code:
12352100
EC Number:
203-468-6
MDL number:
Beilstein/REAXYS Number:
605263
Assay:
≥99%
Form:
liquid
$45.40
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Product Name
Ethylenediamine, ReagentPlus®, ≥99%
agency
suitable for EPA 300
Quality Level
vapor density
2.07 (vs air)
vapor pressure
10 mmHg ( 20 °C)
product line
ReagentPlus®
assay
≥99%
form
liquid
autoignition temp.
716 °F
expl. lim.
16 %
refractive index
n20/D 1.4565 (lit.)
bp
118 °C (lit.)
mp
8.5 °C (lit.)
solubility
H2O: soluble at
density
0.899 g/mL at 25 °C (lit.)
functional group
amine
SMILES string
NCCN
InChI
1S/C2H8N2/c3-1-2-4/h1-4H2
InChI key
PIICEJLVQHRZGT-UHFFFAOYSA-N
Gene Information
human ... FNTA(2339)
General description
Application
Ethylenediamine (1,2-Diaminoethane, DAE) can be used as a reagent to prepare various metal ion complexes. For instance, DAE reacts with chromium(II) salts forms a Cr(II)/DAE complex, which is used as an efficient reducing agent for the reduction of primary alkyl halides to alkanes, and aryl bromides or iodides to arenes. This complex is also used to reduce β-substituted alkyl halides and epoxides to alkenes.
DAE can also be used in the following reduction reactions:
DAE can also be used in the following reduction reactions:
- DAE/Borane (1:1) complex is used as a highly selective reducing agent for the conversion of cinnamaldehyde to cinnamyl alcohol.
- DAE/Li complex is used as an efficient reagent for the reduction of alkenes, aromatic hydrocarbons, phenols, and alcohols.
Ethylenediamine (en) has been used in the following process:
- Synthesis of nucleus pulposus (NP)-like collagen-glycosaminoglycans (CG) core.[4]
- Surface modification of epoxy-activated cryogel.[5]
- Alteration of the surface of carbon nanoparticles (CNPs) to generate CNPs-ethylene.[6]
- Surface modification of triazolate-bridged metal-organic framework.[7]
- As a solvent in the synthesis of ZnS (zinc sulfide) and ZnSe (zinc selenium) precursors by solvothermal process.[8]
- As a reactant in the synthesis of Pd/C-ethylenediamine complex catalyst.
- As a chelating agent in the synthesis of β-Co(OH)2 nanocrystals.[9]
- Synthesis of ethylenediamine-templated iron arsenates and fluoroarsenates.[10]
- As a template agent and coordination agent in the synthesis of CdS (cadmium sulfide) nanocrystals.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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This Item | |||
|---|---|---|---|
| assay ≥99% | assay >99% | assay 98.6% (Gew) | assay ≥99.5% |
| solubility H2O: soluble at | solubility H2O: soluble at | solubility H2O: soluble at | solubility ethanol: soluble(lit.), water: miscible(lit.), water: very soluble(lit.) |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
| density 0.899 g/mL at 25 °C (lit.) | density 0.899 g/mL at 25 °C (lit.) | density 0.899 g/mL at 25 °C (lit.) | density 0.899 g/mL at 25 °C (lit.) |
| mp 8.5 °C (lit.) | mp 8.5 °C (lit.) | mp 8.5 °C (lit.) | mp 8.5 °C (lit.) |
| bp 118 °C (lit.) | bp 118 °C (lit.) | bp 118 °C (lit.) | bp 118 °C (lit.) |
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Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Resp. Sens. 1B - Skin Corr. 1B - Skin Sens. 1B
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
100.4 °F - closed cup
flash_point_c
38 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Related Content
This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.
Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.
1, 2-Diaminoethane
Kostikov RR
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Synthesis of CdS nanorods by an ethylenediamine assisted hydrothermal method for photocatalytic hydrogen evolution.
Li Y, et al.
The Journal of Physical Chemistry C, 113(21), 9352-9358 (2009)
Aude Demessence et al.
Journal of the American Chemical Society, 131(25), 8784-8786 (2009-06-10)
Reaction of CuCl(2) x 2 H(2)O with 1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene (H(3)BTTri) in DMF at 100 degrees C generates the metal-organic framework H(3)[(Cu(4)Cl)(3)(BTTri)(8)(DMF)(12)] x 7 DMF x 76 H(2)O (1-DMF). The sodalite-type structure of the framework consists of BTTri(3-)-linked [Cu(4)Cl](7+) square clusters in
Global Trade Item Number
| SKU | GTIN |
|---|---|
| E26266-4X100ML | 04061837358555 |
| E26266-5ML | 04061833602836 |
| E26266-1L | 04061833602812 |
| E26266-100ML | 04061833602805 |
| E26266-2.5L | 04061833602829 |
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Qual o método volumétrico realizado para a ánalise da reagente em questão??
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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The concentration of the solution
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This product is a neat or pure liquid with a reported density of 0.899 g/mL and a molecular weight of 60.10 g/mol. Assuming a 99.9% purity, the concentration is approximately 14.94 M. The molarity may be determined using the molecular weight, density, and lot specific purity as demonstrated in the calculation below:
(Density x 1000 x w/w% / Molecular Weight)Helpful?
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