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MilliporeSigma

M1296

Malonic acid

reagent grade, 99%, powder or crystals, chunks, granular, ReagentPlus®

Synonym(s):

Propanedioic acid

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5 G

$36.50

100 G

$90.20

500 G

$272.00

2.5 KG

$805.00

5 KG

$1,020.00

$36.50


Available to ship onJanuary 13, 2026Details


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About This Item

Linear Formula:
CH2(COOH)2
CAS Number:
Molecular Weight:
104.06
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
205-503-0
MDL number:
Beilstein/REAXYS Number:
1751370

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Product Name

Malonic acid, ReagentPlus®, 99%

InChI key

OFOBLEOULBTSOW-UHFFFAOYSA-N

InChI

1S/C3H4O4/c4-2(5)1-3(6)7/h1H2,(H,4,5)(H,6,7)

SMILES string

OC(=O)CC(O)=O

grade

reagent grade

vapor pressure

0.002 hPa ( 25 °C)

product line

ReagentPlus®

assay

99%

form

chunks
granular
powder or crystals

bp

215 °C/18.66 hPa

mp

132-135 °C (dec.) (lit.)

solubility

1 M NaOH: 100 mg/mL, clear to slightly hazy, colorless to faintly yellow

density

1,6 g/cm3

functional group

carboxylic acid

Quality Level

Gene Information

human ... SRC(6714)

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1 of 4

This Item
7925358.0038768714
grade

reagent grade

grade

anhydrous

grade

for synthesis

grade

certified reference material, TraceCERT®

assay

99%

assay

99%

assay

-

assay

-

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

300

form

chunks, powder or crystals, granular

form

powder

form

-

form

-

solubility

1 M NaOH: 100 mg/mL, clear to slightly hazy, colorless to faintly yellow

solubility

1 M NaOH: 100 mg/mL, clear to slightly hazy, colorless to faintly yellow

solubility

-

solubility

-

mp

132-135 °C (dec.) (lit.)

mp

132-135 °C (dec.) (lit.)

mp

132-135 °C (dec.) (lit.)

mp

132-135 °C (dec.) (lit.)

Application

Malonic acid may be used as a cross-linking agent between corn starch and potato starch to improve its mechanical properties.[1]

General description

Malonic acid (MA), also known as propanedioic acid, is a dicarboxylic acid. The crystals of MA are triclinic at room temperature.[2][3] The oxidation of malonic acid by cerium (IV) in sulfuric acid solution has been studied.[4] The reaction kinetics of the photocatalytic decomposition of MA in aqueous suspensions of titanium dioxide (TiO2) have been described.[5]

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

314.6 °F - closed cup

flash_point_c

157 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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The crystal structure of malonic acid.
Goedkoop JA and MacGillavry CH.
Acta Crystallographica, 10(2), 125-127 (1957)
On the oxidation of malonic acid by ceric ions.
Barkin S, et al.
International Journal of Chemical Kinetics, 10(6), 619-636 (1978)
Photocatalytic degradation of malonic acid in aqueous suspensions of titanium dioxide: an initial kinetic investigation of CO2 photogeneration.
Inel Y and Okte AN.
Journal of Photochemistry and Photobiology A: Chemistry, 96(1), 175-180 (1996)
Refinement of the crystal structure of malonic acid, C3H4O4.
Jagannathan NR, et al.
Journal of Chemical Crystallography, 24(1), 75-78 (1994)
Bogdan Belgorodsky et al.
Bioconjugate chemistry, 16(5), 1058-1062 (2005-09-22)
The preparation and characterization of the stable human serum albumin (HSA)-C3 isomer of tris-malonic acid [C60]fullerene complex is reported. Other than the anti-fullerene antibody, a stable protein-fullerene complex with a native protein has never been observed. This study may provide

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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