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159417

Hydroxylamine hydrochloride

ReagentPlus®, 99%

Hydroxylamine hydrochloride

Synonym(s):

Hydroxylammonium chloride

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100 g

Available to ship TODAYfromMILWAUKEE

$48.80
500 g

Available to ship TODAYfromMILWAUKEE

$108.00
1 kg

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$190.00
3 kg

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$401.00

About This Item

Linear Formula:
NH2OH · HCl
CAS Number:
Molecular Weight:
69.49
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
EC Number:
226-798-2
Beilstein/REAXYS Number:
3539763
MDL number:
Assay:
99%
Form:
crystalline

$48.80


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vapor pressure

0.001 hPa ( 50 °C)

Quality Segment

product line

ReagentPlus®

assay

99%

form

crystalline

technique(s)

inhibition assay: suitable

pH

2.5-3.5 (20 °C, 50 g/L)

mp

155-157 °C (dec.) (lit.)

density

1.67 g/mL at 25 °C (lit.)

SMILES string

Cl.NO

InChI

1S/ClH.H3NO/c;1-2/h1H;2H,1H2

InChI key

WTDHULULXKLSOZ-UHFFFAOYSA-N

General description

Hydroxylamine hydrochloride (NH2OH.HCl) is a hygroscopic salt widely used as a reactant in electrophilic substitution reactions, oxidation, and reduction reactions. It is also used in the synthesis of nitriles, pyrazoles, isoxazoles, nitrones, and pyridine.
Hydroxylamine hydrochloride (Hydroxylammonium chloride) participates in the synthesis of 1,2,4-oxadiazoles, secondary amides and tertiary amides.[1]

Application

Hydroxylamine hydrochloride can be used as a reactant:
  • in the synthesis of primary amides from aldehydes in the presence of cesium carbonate (Cs2CO3) as a catalyst.
  • in the conversion of alicyclic /aliphatic carbonyl compounds and the aromatic aldehydes into corresponding oximes.
  • in the one-pot synthesis of nitriles from aldehydes in the presence of sodium sulfate (anhyd) and sodium bicarbonate catalysts.
  • It can also be used as a reducing agent in the preparation of single-layer reduced graphene oxide (RGO) sheets and films.

Biochem/physiol Actions

MAO inhibitor; inhibits platelet aggregation.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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1 of 1

This Item
55460911119379921
form

crystalline

form

powder or crystals

form

powder

form

powder, crystals or chunks

assay

99%

assay

≥99.0% (RT)

assay

98.0%

assay

99.995% trace metals basis

Quality Level

100

Quality Level

300

Quality Level

-

Quality Level

200

density

1.67 g/mL at 25 °C (lit.)

density

1.67 g/mL at 25 °C (lit.)

density

1.67 g/mL at 25 °C (lit.)

density

1.67 g/mL at 25 °C (lit.)

vapor pressure

0.001 hPa ( 50 °C)

vapor pressure

0.001 hPa ( 50 °C)

vapor pressure

0.001 hPa ( 50 °C)

vapor pressure

-

pH

2.5-3.5 (20 °C, 50 g/L)

pH

2.5-3.5 (25 °C, 50 mg/mL in H2O)

pH

2.5-3.5 (20 °C, 50 g/L)

pH

2.5-3.5 (20 °C, 50 g/L)


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signalword

Warning

target_organs

spleen

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2

Storage Class

8B - Non-combustible corrosive hazardous materials



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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