MilliporeSigma
All Photos(1)

Documents

208566

Sigma-Aldrich

Titanium(IV) chloride

ReagentPlus®, 99.9% trace metals basis

Sign Into View Organizational & Contract Pricing

Synonym(s):
TTC, Titanium tetrachloride
Linear Formula:
TiCl4
CAS Number:
Molecular Weight:
189.68
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.55

vapor pressure

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

Quality Level

100
200

product line

ReagentPlus®

assay

99.9% trace metals basis

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

bp

135-136 °C (lit.)

mp

−25 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

Looking for similar products? Visit Product Comparison Guide

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
254312697079404985
vibrant-m

208566

Titanium(IV) chloride

vibrant-m

254312

Titanium(IV) chloride

vibrant-m

697079

Titanium tetrachloride

vibrant-m

404985

Titanium(IV) chloride solution

Quality Level

100, 200

Quality Level

100

Quality Level

100

Quality Level

100

assay

99.9% trace metals basis

assay

≥99.995% trace metals basis

assay

≥99.995% (trace metals analysis)

assay

-

density

1.73 g/mL at 20 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

density

1.73 g/mL at 20 °C (lit.)

density

1.099 g/mL at 25 °C

vapor pressure

50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)

vapor pressure

50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)

vapor pressure

50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)

vapor pressure

-

mp

−25 °C (lit.)

mp

−25 °C (lit.)

mp

−25 °C (lit.)

mp

-

General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) have been used for the synthesis of nanosized titanium dioxide.

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Along with sodium borohydride, it forms an effective reagent for the reduction of:
  • carboxylic acid and acyl chloride to alcohols
  • carboxamides, oximes and lactams to amines
  • sulfoxides to sulfides
Titanium(IV) chloride (TiCl4) has been used as a precursor for the synthesis of Ag-TiO2@polyethylene glycol (PEG) nanoparticles. TiCl4 may also be used as one of the constituents to synthesize TiO2/Al2O3 binary oxide materials and N-(10-oxo-vinylanthracen-9-(10H)-ylidene)cyanamide.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

CorrosionSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Documents related to the products that you have purchased in the past have been gathered in the Document Library for your convenience.

Visit the Document Library

Difficulty Finding Your Product Or Lot/Batch Number?

Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

Not Finding What You Are Looking For?

In some cases, a COA may not be available online. If your search was unable to find the COA you can request one.

Request COA

Customers Also Viewed

Slide 1 of 4

1 of 4

Titanium(IV) butoxide reagent grade, 97%

Sigma-Aldrich

244112

Titanium(IV) butoxide

Titanium(IV) fluoride

Sigma-Aldrich

333239

Titanium(IV) fluoride

Titanium(IV) iodide anhydrous, powder, 99.99% trace metals basis

Sigma-Aldrich

458449

Titanium(IV) iodide

Tin(IV) chloride 98%

Sigma-Aldrich

208930

Tin(IV) chloride

Gaofei Xiao et al.
Journal of environmental sciences (China), 60, 14-23 (2017-10-17)
TiO
Reduction of some functional groups with titanium (IV) chloride/sodium borohydride.
Kano S, et al.
Synthesis, 1980(09), 695-697 (1980)
Scalable hybrid chemical manufacture to photothermal therapy: PEG-capped phototransducers
Byeon, Jeong Hoon
Scientific Reports, 6 (2016)
Influence of the sol-gel preparation method on the photocatalytic NO oxidation performance of TiO2/Al2O3 binary oxides.
Polat M, et al.
Catalysis Today, 241, 25-32 (2015)
Poly [N-(10-oxo-2-vinylanthracen-9(10H)-ylidene) cyanamide] as a novel cathode material for li-organic batteries.
Schmidt D, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 53(21), 2517-2523 (2015)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service