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209619

Potassium carbonate

ACS reagent, ≥99.0%

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Size/SKUAvailabilityPrice
100 g
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$63.90
500 g
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$115.00
2.5 kg
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$398.00
12 kg
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$1,050.00

About This Item

Linear Formula:
K2CO3
CAS Number:
Molecular Weight:
138.21
UNSPSC Code:
12352302
NACRES:
NA.21
PubChem Substance ID:
EC Number:
209-529-3
Beilstein/REAXYS Number:
4267587
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Form:
powder or crystals

$63.90


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grade

ACS reagent

Quality Segment

assay

≥99.0%

form

powder or crystals

impurities

≤0.004% S compounds as (SO42-) , ≤0.005% silica, ≤0.01% insolubles

pH

11-13 (25 °C, 138 g/L)

mp

891 °C (lit.)

anion traces

chloride (Cl-): ≤0.003%, phosphate (PO43-): ≤0.001%

cation traces

Ca: ≤0.005%, Fe: ≤5 ppm, Mg: ≤0.002%, Na: ≤0.02%, heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

[K+].[K+].[O-]C([O-])=O

InChI

1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

BWHMMNNQKKPAPP-UHFFFAOYSA-L

General description

Potassium carbonate is an inorganic base. It participates as a base in the palladacycle catalyzed Heck reaction of chlorobenzene with styrene. Addition of amino acids (glycine, sarcosine and proline) to K2CO3 (solvent) promotes the absorption of CO2.

Application

Potassium carbonate has been used in the preparation of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone, a disulfonated diamine monomer.
It may be used in the following studies:
  • As a reagent in the synthesis of polysubstituted iodobenzene derivatives.[1]
  • As a base for the synthesis of high molecular weight homopolymers and copolymers derived from various bisphenols.
  • As a base for the Suzuki coupling of aryl halides with aryl boronic acids.
  • The Heck reaction of styrene and bromobenzene.

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

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1 of 1

This Item
60109310263P5833
form

powder or crystals

form

powder or crystals

form

solid

form

powder

assay

≥99.0%

assay

≥99.0% (T)

assay

99%

assay

≥99.0%

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

-

grade

-

anion traces

chloride (Cl-): ≤0.003%, phosphate (PO43-): ≤0.001%

anion traces

chloride (Cl-): ≤30 mg/kg, phosphate (PO43-): ≤10 mg/kg, silicate (as SiO2): ≤50 mg/kg

anion traces

-

anion traces

chloride (Cl-): ≤0.005%, sulfate (SO42-): ≤0.02%

mp

891 °C (lit.)

mp

891 °C (lit.)

mp

891 °C (lit.)

mp

891 °C (lit.)


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pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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