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215473

Ammonium cerium(IV) nitrate

ACS reagent, ≥98.5%

Synonym(s):

CAN, Ceric ammonium nitrate

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50 g

Available to ship TODAYfromMILWAUKEE

$70.00
250 g

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$211.00
500 g

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$320.00

About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
Molecular Weight:
548.22
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
240-827-6
MDL number:
Assay:
≥98.5%
Grade:
ACS reagent
Form:
powder or crystals

$70.00


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grade

ACS reagent

Quality Level

assay

≥98.5%

form

powder or crystals

reaction suitability

reagent type: oxidant

impurities

≤0.05% insol. dil. H2SO4

anion traces

chloride (Cl-): ≤0.01%, phosphate (PO43-): ≤0.02%

cation traces

Fe: ≤0.005%

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

Application

Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.

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2295471.9331005-2170
form

powder or crystals

form

crystalline

form

-

form

crystalline

assay

≥98.5%

assay

≥99.99% trace metals basis

assay

-

assay

≥95.0%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

-

grade

ACS reagent

grade

-

grade

ACS reagent

grade

JIS special grade

cation traces

Fe: ≤0.005%

cation traces

-

cation traces

-

cation traces

-

impurities

≤0.05% insol. dil. H2SO4

impurities

≤100.0 ppm Trace Metal Analysis

impurities

-

impurities

-


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class

5.1B - Oxidizing hazardous materials



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Selective and efficient oxidation of sulfides to sulfoxides using ammonium cerium (IV) nitrate in the presence of a catalytic amount of KBr or NaBr.
Zolfigol MA, et al.
Monatshefte fur Chemie / Chemical Monthly, 139(8), 895--895- (2008)
A New. ALPHA.-Iodination of Ketones Using Iodine-Ammonium Cerium (IV) Nitrate in Alcohol or Acetic Acid.
Horiuchi CA and Kiji S.
Bulletin of the Chemical Society of Japan, 70(2), 421-426 (1997)
Polyethylene glycol (PEG) mediated green synthesis of 2, 5-disubstituted 1, 3, 4-oxadiazoles catalyzed by ceric ammonium nitrate (CAN).
Kidwai M, et al.
Green Chemistry Letters and Reviews, 31(1), 55-59 (2010)



Global Trade Item Number

SKUGTIN
215473-500G04061838773760
215473-250G04061838773753
215473-50G04061838773777

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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