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221716

Ammonium oxalate monohydrate

ACS reagent, ≥99%

Synonym(s):

Oxalic acid diammonium salt

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100 g

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$57.10
500 g

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2.5 kg
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$659.00

About This Item

Linear Formula:
(NH4)2C2O4 · H2O
CAS Number:
Molecular Weight:
142.11
UNSPSC Code:
12352300
NACRES:
NB.24
PubChem Substance ID:
EC Number:
238-135-4
Beilstein/REAXYS Number:
3759830
MDL number:
Assay:
≥99%, 99.0-101.0% (ACS specification)
Grade:
ACS reagent
Form:
crystalline powder, crystals or granules

$57.10


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grade

ACS reagent

Quality Level

vapor pressure

<0.1 hPa ( 20 °C)

assay

≥99%, 99.0-101.0% (ACS specification)

form

crystalline powder, crystals or granules

impurities

≤0.005% insolubles

ign. residue

≤0.02%

pH

6-7 (25 °C, 14.2 g/L)

mp

133 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤0.002%, sulfate (SO42-): ≤0.002%

cation traces

Fe: ≤2 ppm, heavy metals: ≤5 ppm (by ICP)

SMILES string

OC(C(O)=O)=O.N.O.N

InChI

1S/C2H2O4.2H3N.H2O/c3-1(4)2(5)6;;;/h(H,3,4)(H,5,6);2*1H3;1H2

InChI key

MSMNVXKYCPHLLN-UHFFFAOYSA-N

General description

Ammonium oxalate monohydrate is a diammonium salt of oxalic acid. Its refined crystal structure has been investigated by three-dimensional diffraction studies. Influence of bivalent [Mn(II), Co(II), Ni(II)] and trivalent cations [Fe(III), Cr(III)] impurities on the growth rates of ammonium oxalate monohydrate crystals has been described. Its space group and unit cell parameters have been analyzed by neutron diffraction studies. Its IR spectra have been compared with that of isolated coal-solubilizing agent (CSA).[1]

Application

Ammonium oxalate monohydrate may be used in the preparation of tetramethylammonium oxalate.

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This Item
3230437974301-4870
form

crystalline powder, crystals or granules

form

crystalline

form

powder

form

crystalline

assay

≥99%, 99.0-101.0% (ACS specification)

assay

99.5-101.0%

assay

≥99.99% trace metals basis

assay

≥99.5%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

-

grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

-

grade

JIS special grade

impurities

≤0.005% insolubles

impurities

≤0.005% in water insoluble matters

impurities

≤100.0 ppm Trace Metal Analysis

impurities

-

vapor pressure

<0.1 hPa ( 20 °C)

vapor pressure

<0.1 hPa ( 20 °C)

vapor pressure

-

vapor pressure

-


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Yeonho Kim et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(46), 10510-10518 (2020-03-27)
In this work, environmentally friendly photocatalysts with attractive catalytic properties are reported that have been prepared by introducing SnO2 quantum dots (QDs) directly onto ZnSe(N2 H4 )0.5 substrates to induce advantageous charge separation. The SnO2 /ZnSe(N2 H4 )0.5 nanocomposites could
Sina Matavos-Aramyan et al.
Free radical biology & medicine, 106, 158-167 (2017-02-19)
Three novel modified advanced oxidation process systems including ascorbic acid-, pro-oxidants- and ascorbic acid-pro-oxidants-modified Fenton system were utilized to study the disinfection efficiency on Cryptosporidium-contaminated drinking water samples. Different concentrations of divalent and trivalent iron ions, hydrogen peroxide, ascorbic acid
A convenient method for preparation of quaternary ammonium salts.
Markowitz M.
The Journal of Organic Chemistry, 22(8), 983-984 (1957)



Global Trade Item Number

SKUGTIN
675385-1G04061825768229
221716-100G04061838777485
221716-2.5KG04061832562766
221716-500G04061838777492

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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