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223336

Sodium tungstate dihydrate

ACS reagent, ≥99%

Synonym(s):

Tungstic acid sodium salt dihydrate

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5 g

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$46.75
100 g

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$153.00
500 g

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$474.00

About This Item

Linear Formula:
Na2WO4 · 2H2O
CAS Number:
Molecular Weight:
329.85
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
236-743-4
MDL number:
Assay:
≥99%
Grade:
ACS reagent
Form:
crystalline powder

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grade

ACS reagent

Quality Segment

assay

≥99%

form

crystalline powder

reaction suitability

reagent type: catalyst
core: tungsten

impurities

≤0.01% insolubles, ≤0.02 meq/g Titr. free base

pH

9-11.5 (20 °C, 100 g/L)

mp

698 °C (lit.)

anion traces

chloride (Cl-): ≤0.005%, sulfate (SO42-): ≤0.01%

cation traces

Mo: ≤0.001%, heavy metals and iron (as Pb): ≤0.001%

SMILES string

O.O.[Na+].[Na+].[O-][W]([O-])(=O)=O

InChI

1S/2Na.2H2O.4O.W/h;;2*1H2;;;;;/q2*+1;;;;;2*-1;

InChI key

WPZFLQRLSGVIAA-UHFFFAOYSA-N

General description

Sodium tungstate dihydrate is a hydrated sodium salt of tungstic acid. It participates as a catalyst in the preparation of various epoxides. Various crystallographic properties of sodium tungstate dihydrate have been analyzed.

Application

Combines with hydrogen peroxide for the oxidation of secondary amines to nitrones.
Sodium tungstate dihydrate (Na2WO4.2H2O) may be employed in the following studies:
  • As a derivatization reagent for the determination of hydrogen peroxide by a fluorimetric method.[1]
  • Synthesis of N-hydroxy-desferrioxamine B, a metabolite of the microbial product desferrioxamine B.[2]
  • Preparation of highly crystalline CaMoO4, SrMoO4, CaWO4 and SrWO4 nanoparticles.
Sodium tungstate dihydrate may be used in the preparation of aqueous sols of tungsten oxide dihydrate.

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This Item
28-46407206972069
form

crystalline powder

form

crystals

form

crystals

form

crystals

assay

≥99%

assay

99.0-100.5

assay

≥99.0% (T)

assay

≥99.0% (T)

grade

ACS reagent

grade

JIS special grade

grade

reagent grade

grade

reagent grade

impurities

≤0.01% insolubles, ≤0.02 meq/g Titr. free base

impurities

-

impurities

insoluble matter, passes filter test, ≤0.001% total nitrogen (N), ≤0.1% free alkali (as NaOH)

impurities

insoluble matter, passes filter test, ≤0.001% total nitrogen (N), ≤0.1% free alkali (as NaOH)

anion traces

chloride (Cl-): ≤0.005%, sulfate (SO42-): ≤0.01%

anion traces

-

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤100 mg/kg

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤100 mg/kg

pH

9-11.5 (20 °C, 100 g/L)

pH

9.0-11.5 (20 °C, 100 g/L)

pH

9.5-11.5 (25 °C, 1 M in H2O)

pH

9.5-11.5 (25 °C, 1 M in H2O)


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

13 - Non Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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