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MilliporeSigma

233714

Sodium bisulfate monohydrate

ReagentPlus®, 99%

Synonym(s):

Sodium hydrogen sulfate monohydrate

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100 G

$77.80

500 G

$176.00

1 KG

$221.00

$77.80


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About This Item

Linear Formula:
NaHSO4 · H2O
CAS Number:
Molecular Weight:
138.08
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-665-7
MDL number:
Assay:
99%
Form:
moist crystals

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InChI key

JXHZRQHZVYDRGX-UHFFFAOYSA-M

InChI

1S/Na.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+1;;/p-1

SMILES string

[Na+].[H]O[H].OS([O-])(=O)=O

product line

ReagentPlus®

assay

99%

form

moist crystals

Quality Level

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1 of 4

This Item
716571.06350769339
form

moist crystals

form

powder or crystals

form

-

form

crystalline

assay

99%

assay

≥99.0% (T)

assay

-

assay

≥99% (T)

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

product line

ReagentPlus®

product line

-

product line

-

product line

-

General description

Sodium bisulfate monohydrate can be used as a reagent for the oxidation of benzylic alcohols to aldehydes and ketones, diarylcarbazides to diaryl carbazones, 1,2-dihydroquinolines to quinoline derivatives, and 1,4-dihydropyridines to pyridine derivatives[1][2][3][4]. It can also be used as a catalyst in the esterification of carboxylic acids and alcohols to synthesize esters[5]. Additionally, it is an effective oxygen scavenger to inhibit corrosion[6].

Application


  • Preservative and Sanitizer in Food Microbiology: Sodium bisulfate monohydrate is effectively used as a preservative in apple juice and as an alternative sanitizer for washing cherry tomatoes. Its antimicrobial properties help control pathogens like Listeria monocytogenes and Escherichia coli, ensuring food safety. This application is crucial for chemists working in food microbiology and safety, highlighting the compound′s role in maintaining the quality and safety of food products (Chen et al., International Journal of Food Microbiology, 2022).

  • One-Step Hydrolysis for Xylooligosaccharides Production: Sodium bisulfate monohydrate is employed in a one-step hydrolysis process for the efficient production of xylooligosaccharides from poplar. This method enhances the yield and purity of xylooligosaccharides, which are valuable in various industrial applications, including food additives and pharmaceuticals. This research underscores its importance in bioprocessing and green chemistry initiatives (Liao et al., SSRN Electronic Journal, 2022).

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Disclaimer

The product is not intended for use as a biocide under global biocide regulations, including but not limited to the US EPA′s Federal Insecticide Fungicide and Rodenticide Act, the European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR), and others.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Oxidation of 1, 2-dihydroquinolines under mild and heterogeneous conditions
Damavandi J, et al.
Synthetic Communications, 31, 3183-3187 (2001)
Selective and efficient oxidation of diaryl carbazide to diaryl carbazone with NaNO2/NaHSO4? H2O/SiO2
Li X, et al.
J. Chem. Res. (M), 2002, 234-235 (2002)
The role of protein extracts in the induction of disease in Acanthaster planci
Rivera-Posada J, et al.
Journal of Experimental Marine Biology and Ecology, 429, 1-6 (2012)
Oxidation of 1, 4-dihydropyridines under mild and heterogeneous conditions
Zolfigol M, et al.
Synthetic Communications, 30, 2945-2950 (2000)
NaBrO3/NaHSO4.H2O as a versatile reagent system for the oxidation of benzylic alcohols and aldehydes
Shirini F, et al.
Synthetic Communications, 36, 2833-2840 (2006)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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